429147
(Acetylacetonato)dicarbonyliridium(I)
Synonym(s):
Dicarbonyl(2,4-pentanedionato)iridium
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About This Item
Linear Formula:
Ir(acac)(CO2)
CAS Number:
Molecular Weight:
347.35
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
reaction suitability
core: iridium
reagent type: catalyst
SMILES string
[C-]#[O+].[C-]#[O+].CC(=O)\C=C(\C)O[Ir]
InChI
1S/C5H8O2.2CO.Ir/c1-4(6)3-5(2)7;2*1-2;/h3,6H,1-2H3;;;/q;;;+1/p-1/b4-3-;;;
InChI key
DFIAYCFHPDOZLK-FGSKAQBVSA-M
Application
Catalyst for isomerization and anti-Markovnikov arylation of olefins
Reactant for:
Reactant for:
- Oxidative addition of perfluoroalkyl iodides
- Synthesis of iridium heterocycles
- Scaffolding of iridium complexes
- Metal carbonyl cluster synthesis
- Mixed-bridged bimetallic d8 complex synthesis
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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