424838
Triphenylgermanium hydride
Synonym(s):
Triphenylgermane, Triphenylgermanyl hydride
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About This Item
Linear Formula:
(C6H5)3GeH
CAS Number:
Molecular Weight:
304.96
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
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form
powder or crystals
solid
reaction suitability
core: germanium
reagent type: reductant
mp
40-43 °C (lit.)
SMILES string
c1ccc(cc1)[GeH](c2ccccc2)c3ccccc3
InChI
1S/C18H16Ge/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
InChI key
NXHORDQDUDIXOS-UHFFFAOYSA-N
General description
Triphenylgermanium hydride is a hydrogen donor.
Application
It may be used in the isomerization of (Z) alkene.1 TEMPO (2,2,6,6-Tetramethylpiperidinyloxy) reacts with triphenylgermanium hydride to form its corresponding germyl radical. 2
Packaging
Packaged in glass bottles
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The dihydrido germyl complex cis,fac-[Rh(GePh3)(H)2(PEt3)3] (2) was synthesized by an oxidative addition of HGePh3 at [Rh(H)(PEt3)3] (1). Treatment of 2 with neohexene generated the rhodium(i) germyl complex [Rh(GePh3)(PEt3)3] (3). Alternatively, treatment of the methyl complex [Rh(CH3)(PEt3)3] (4) with HGePh3 furnished
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