399191
Rhodium(II) trifluoroacetate dimer
Synonym(s):
Trifluoroacetic acid rhodium(II) salt dimer
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About This Item
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form
powder
reaction suitability
reagent type: catalyst
SMILES string
FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F.FC(F)(F)C(=O)O[Rh]OC(=O)C(F)(F)F
InChI
1S/4C2HF3O2.2Rh/c4*3-2(4,5)1(6)7;;/h4*(H,6,7);;/q;;;;2*+2/p-4
InChI key
PQEXTYUESSEHKW-UHFFFAOYSA-J
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Application
Used in the preparation of isomerically pure α,β-unsaturated carbonyl compounds and the preparation of building blocks for one-, two-, and three-dimensional molecular solids.
Other Notes
Contains a trace amount of rhodium acetate
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A Convenient Method for the Preparation of (Z)-alpha,beta-Unsaturated Carbonyl Compounds.
The Journal of organic chemistry, 61(8), 2908-2910 (1996-04-19)
Inorganic chemistry, 35(11), 3183-3187 (1996-05-22)
The complexes trans-[MI(2)(CNC(6)H(4)-CN-4)(2)], (M = Pd and Pt), trans-[FeI(2)L(4)] (L = CNC(6)H(4)-CN-4 and CNC(6)H(2)-Me(2)-2,6-CN-4), and [Mn(CNC(6)H(4)-CN-4)(6)][SO(3)CF(3)] were prepared. The compounds are thermally stable up to 230 degrees C or higher. The molecular structure of trans-[FeI(2)(CNC(6)H(4)-CN-4)(4)] was determined by X-ray crystallography:
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