72240
Aluminum-nickel alloy
purum, 50% Al basis, 50% Ni basis
Synonym(s):
Nickel-aluminum alloy, Raney®-Nickel alloy
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About This Item
CAS Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
grade
purum
form
powder
composition
Al, 50%
Ni, 50%
reaction suitability
core: nickel
reagent type: catalyst
SMILES string
[Al].[Ni]
InChI
1S/Al.Ni
InChI key
NPXOKRUENSOPAO-UHFFFAOYSA-N
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Application
Aluminum-nickel alloy can be used:
- For the reduction of nitriles, nitro compounds and oximes to primary amines.
- For the conversion of carbonyl compounds to hydrocarbons.
- As a reducing agent to convert Ar-X derivatives to Ar-H compounds.
- For the synthesis of Raney nickel catalyst to be used as an alkylating agent.
- To synthesize non-pyrophoric Ni catalyst by alkali leaching.
- For the synthesis of alloyed skeletal Ni catalysts.
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
replaced by
Product No.
Description
Pricing
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Reduction of carbonyl groups to the corresponding methylenes with Ni-Al alloy in water.
Ishimoto K, et al.
Chemical Communications (Cambridge, England), 89(4), 514-515 (2003)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
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