GF26710680
Rhodium
wire reel, 0.1m, diameter 0.12mm, as drawn, 99.9%
Synonym(s):
Rhodium, RH005105
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About This Item
Empirical Formula (Hill Notation):
Rh
CAS Number:
Molecular Weight:
102.91
MDL number:
UNSPSC Code:
12141738
PubChem Substance ID:
NACRES:
NA.23
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Assay
99.90%
form
wire
manufacturer/tradename
Goodfellow 267-106-80
resistivity
4.33 μΩ-cm, 20°C
L × diam.
0.1 m × 0.12 mm
bp
3727 °C (lit.)
mp
1966 °C (lit.)
density
12.41 g/cm3 (lit.)
SMILES string
[Rh]
InChI
1S/Rh
InChI key
MHOVAHRLVXNVSD-UHFFFAOYSA-N
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General description
For updated SDS information please visit www.goodfellow.com.
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Product of Goodfellow
Storage Class Code
13 - Non Combustible Solids
WGK
nwg
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Huw M L Davies et al.
Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)
This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products
Jan Meine Ernsting et al.
Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)
Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic
Feng Shi et al.
Topics in current chemistry, 292, 123-164 (2010-01-01)
The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation
Huw M L Davies et al.
Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)
This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive
Jean Bouffard et al.
Topics in current chemistry, 292, 231-280 (2010-01-01)
A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms
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