89025
Copper(I) thiophenolate
≥98.0% (RT)
Synonym(s):
PhSCu, Copper(I) thiophenoxide, Phenylthiocopper(I), Thiophenol copper(I) salt
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About This Item
Linear Formula:
C6H5SCu
CAS Number:
Molecular Weight:
172.71
Beilstein:
3709171
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Assay
≥98.0% (RT)
form
solid
reaction suitability
core: copper
reagent type: catalyst
mp
280 °C (dec.) (lit.)
SMILES string
[Cu]Sc1ccccc1
InChI
1S/C6H6S.Cu/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key
PNNJYDODNCALKD-UHFFFAOYSA-M
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Application
Reagents used as the source of nucleophilic phenyl sulfide for preparation of lithiumalkyl(phenylthio)cuprates and organophosphinecopper(I) phenylthiolatecomplexes
Other Notes
Reagent for the simple preparation of lithium (phenylthio)alkyl-cuprates from lithium alkyls, used for conjugate addition to α,β-enones
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Customers Also Viewed
E.J. Corey et al.
Tetrahedron Letters, 4597-4597 (1978)
E. Piers et al.
The Journal of Organic Chemistry, 40, 2694-2694 (1975)
Majetich, G.; Song, J. et al.
The Journal of Organic Chemistry, 58, 1030-1030 (1993)
P.A. Wender et al.
Tetrahedron Letters, 1245-1245 (1977)
G.H. Posner et al.
Synthesis, 662-662 (1974)
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