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791105

Sigma-Aldrich

Zinc chloromethanesulfinate

95% (H-NMR)

Synonym(s):

Baran MCMS Reagent

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About This Item

Empirical Formula (Hill Notation):
C2H4Cl2O4S2Zn
CAS Number:
55066-41-6
Molecular Weight:
292.48
MDL number:
MFCD27952553
UNSPSC Code:
12352101
PubChem Substance ID:
329768259
NACRES:
NA.22

Quality Level

100

Assay

95% (H-NMR)

form

solid

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation
reagent type: diversification reagent

mp

190-195 °C

functional group

chloro
sulfinic acid

storage temp.

2-8°C

SMILES string

ClCS(O[Zn]OS(CCl)=O)=O

InChI

1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2

InChI key

HEKATMPPXNXYJU-UHFFFAOYSA-L

Application

Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM2077
MKBW4915V

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Journal of the American Chemical Society
O'Hara,F.; et. al.
Journal of the American Chemical Society, 135, 12122-12134 null
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Fujiwara, Y.; et al.
Nature, 492, 95-100 (2013)

Articles

Baran Diversinates™

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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