738883
1-Methyl-2-azaadamantane-N-oxyl
97%
Synonym(s):
1-Me-AZADO
About This Item
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Assay
97%
form
solid
greener alternative product characteristics
Catalysis
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mp
87-93 °C
greener alternative category
storage temp.
2-8°C
SMILES string
CC12CC3CC(CC(C3)N1[O])C2
InChI
1S/C10H16NO/c1-10-5-7-2-8(6-10)4-9(3-7)11(10)12/h7-9H,2-6H2,1H3
InChI key
IBNXYCCLPCGKDM-UHFFFAOYSA-N
General description
Application
Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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TEMPO (2,2,6,6-Tetramethylpiperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl) and its derivatives are stable nitroxy radicals used as catalysts in organic oxidation reactions. TEMPO was discovered by Lebedev and Kazarnovskii in 1960. The stable free radical nature of TEMPO is due to the presence of bulky substituent groups, which hinder the reaction of the free radical with other molecules.
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