710466

Bis(2-methoxyphenyl)phosphine

97%

• Synonym(s): Di-o-anisylphosphine
• Empirical Formula (Hill Notation): C₁₄H₁₅O₂P
• CAS Number: 10177-79-4
• Molecular Weight: 246.24
• MDL number: MFCD08064038
• UNSPSC Code: 12352112
• PubChem Substance ID: 329762925
• NACRES: NA.22

Properties

• Assay: 97%
• form: powder
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 86-90 °C
• functional group: phosphine
• SMILES string: COc1ccccc1Pc2ccccc2OC
• InChI: 1S/C14H15O2P/c1-15-11-7-3-5-9-13(11)17-14-10-6-4-8-12(14)16-2/h3-10,17H,1-2H3
• InChI key: HFEAMIKDDWKNAG-UHFFFAOYSA-N

Description

Application

Reactant for:

• Allylation of phenols
• Synthesis of neutral rhodium(I) complexes
• Dinuclear Pd(II) complexes bearing bis-bidentate tetraphos ligands
• CO-ethylene copolymerization reactions
• Suzuki-Miyaura reaction for synthesis of alkyl derivatives phosphine sulfonate (P-O) ligands

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Warning
• Hazard Statements: H228,H315,H319,H335
• Precautionary Statements: P210 - P240 - P241 - P261 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable