671444
1,3-Dimethylimidazolium dimethyl phosphate
≥98.0% (HPLC)
Synonym(s):
[MMIM][DMP]
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About This Item
Empirical Formula (Hill Notation):
C7H15N2O4P
CAS Number:
Molecular Weight:
222.18
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
Quality Level
Assay
≥98.0% (HPLC)
impurities
≤1.0% water
SMILES string
COP([O-])(=O)OC.Cn1cc[n+](C)c1
InChI
1S/C5H9N2.C2H7O4P/c1-6-3-4-7(2)5-6;1-5-7(3,4)6-2/h3-5H,1-2H3;1-2H3,(H,3,4)/q+1;/p-1
InChI key
GSGLHYXFTXGIAQ-UHFFFAOYSA-M
General description
1,3-Dimethylimidazolium dimethyl phosphate is an imidazolium-based phosphoric ionic liquid that can be prepared by reacting 1-methylimidazole with trimethyl phosphate. The pretreatment of sugarcane bagasse with [MMIM][DMP] yields glucose and xylose via enzymatic saccharification.
Application
1,3-Dimethylimidazolium dimethyl phosphate ([MMIM][DMP]) can be used as a catalyst and a solvent for the preparation of ethyl 2-cyano-3-phenylpropenoate from benzaldehyde and ethyl cyanoacetate via Knoevenagel condensation. It can also be used to produce bioethanol from sugarcane bagasse by enzymatic hydrolysis.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible, corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Major improvement in the rate and yield of enzymatic saccharification of sugarcane bagasse via pretreatment with the ionic liquid 1-ethyl-3-methylimidazolium acetate ([Emim][Ac]).
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Bioresource Technology, 102(22), 10505-10509 (2011)
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