Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

559830

Sigma-Aldrich

Methyl-2-benzoylbenzoate

97%

Synonym(s):

2-Benzoylbenzoic acid methyl ester, Methyl o-benzoylbenzoate, o-(Methoxycarbonyl)benzophenone

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
C6H5COC6H4CO2CH3
CAS Number:
606-28-0
Molecular Weight:
240.25
EC Number:
210-112-3
MDL number:
MFCD00017187
UNSPSC Code:
12352100
PubChem Substance ID:
24879647
NACRES:
NA.22

Quality Level

100

Assay

97%

form

solid

mp

48-53 °C (lit.)

SMILES string

COC(=O)c1ccccc1C(=O)c2ccccc2

InChI

1S/C15H12O3/c1-18-15(17)13-10-6-5-9-12(13)14(16)11-7-3-2-4-8-11/h2-10H,1H3

InChI key

NQSMEZJWJJVYOI-UHFFFAOYSA-N

General description

Methyl-2-benzoylbenzoate is a 2-acylarylcarboxylate.
  • It can undergo asymmetric transfer hydrogenation reaction in propanol in the presence of a Ruthenium catalyst.
  • Methyl-2-benzoylbenzoate is formed as one of the reaction products during the reaction between methyl benzoate and lithium 2,2,6,6-tetramethylpiperidide (LiTMP) at -117°C.
  • Methyl-2-benzoylbenzoate can be synthesized from the reaction between corresponding 2-substituted benzoic acid and thionyl chloride in methanol.

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCQ6405
MKCJ1442
MKCG2334
MKCB8172
MKBT1441V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Dipole stabilized carbanions. Reactions of benzoate esters with lithium 2, 2, 6, 6-tetramethylpiperidide.
Upton CJ and Beak P.
The Journal of Organic Chemistry, 40(8), 1094-1098 (1975)
One-Step Synthesis of 1-Oxo- 1,2-dihydroisoquinoline-3-carboxylic Acid Derivatives.
Nunami K, et al.
The Journal of Organic Chemistry, 44(11), 1887-1888 (1979)
Stereoselective synthesis of 3-substituted phtalides via asymmetric transfer hydrogenation using well-defined ruthenium catalysts under neutral conditions.
Everaere K, et al.
Tetrahedron Letters, 42(10), 1899-1901 (2001)
Miwa Morizane et al.
Journal of toxicology and environmental health. Part A, 78(23-24), 1450-1460 (2015-12-23)
A recent in vitro study reported that the photoinitiator 2-isopropylthioxanthone (2-ITX) is an endocrine-disrupting compound (EDC). However, it is not clear whether other photoinitiators such as 1-hydroxycyclohexyl phenyl ketone (1-HCHPK) and 2-methyl-4'-(methylthio)-2-morpholinopropiophenone (MTMP) produce endocrine-disrupting effects. The purpose of this
Miguel A Lago et al.
Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment, 33(3), 518-529 (2016-01-21)
Since the UV ink photoinitiator (PI) isopropylthioxanthone (ITX) was discovered in packaged milk, studies of print contamination have focused primarily on PIs but have also included amine synergists. Many other substances are used or formed during the print process, yet

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service