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451665

Sigma-Aldrich

Copper(II) chloride

anhydrous, powder, ≥99.995% trace metals basis

Synonym(s):

Cupric chloride

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About This Item

Linear Formula:
CuCl2
CAS Number:
7447-39-4
Molecular Weight:
134.45
EC Number:
231-210-2
MDL number:
MFCD00010972
UNSPSC Code:
12352302
PubChem Substance ID:
24868644
NACRES:
NA.23

grade

anhydrous

Assay

≥99.995% trace metals basis

form

powder

impurities

≤50.0 ppm Trace Metal Analysis

mp

620 °C (lit.)

density

3.386 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

Cl[Cu]Cl

InChI

1S/2ClH.Cu/h2*1H;/q;;+2/p-2

InChI key

ORTQZVOHEJQUHG-UHFFFAOYSA-L

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General description

CuCl2 was used in studies investigating pleural fibrosis resulting from chronic inhalation of indium phosphide (InP) particles in mice.

Application

Catalyst for oxidation of alcohols under aerobic conditions.

Modified Markó′s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature
Effective catalyst for the tetrahydropyranylation of alcohols, using mild conditions and in high yields.

accessory

Product No.
Description
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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCC4787
MKCC1888
MKCB5436
MKCB5434
MKBX5794V

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Bhalerao, U.T. et al.
Synthetic Communications, 26, 3081-3081 (1996)
Pieter Spincemaille et al.
Toxicology and applied pharmacology, 280(2), 345-351 (2014-08-20)
Wilson disease (WD) is caused by accumulation of excess copper (Cu) due to a mutation in the gene encoding the liver Cu transporter ATP7B, and is characterized by acute liver failure or cirrhosis and neuronal cell death. We investigated the
Su-Jeong Kim et al.
Free radical biology & medicine, 53(4), 936-950 (2012-06-12)
Loss-of-function mutations in the PARK7/DJ-1 gene cause early onset autosomal-recessive Parkinson disease. DJ-1 has been implicated in protection of neurons from oxidative stress and in regulation of transcriptional activity. However, whether there is a relationship between the subcellular localization of
Landon John G Edgar et al.
Organic letters, 14(16), 4226-4229 (2012-08-01)
Glycosyl 1-phosphates enriched in the α-anomer are obtained without the use of protecting groups in two steps starting from the free hemiacetal. Condensation of free hemiacetals with toluenesulfonylhydrazide yields a range of glycosylsulfonohydrazide donors which can be oxidized using cupric
Mónica João Barros Amorim et al.
Environmental pollution (Barking, Essex : 1987), 164, 164-168 (2012-03-01)
Environmental effects of copper nanoparticles are little studied in terrestrial ecosystems. In the present article, the toxicity of copper nanoparticles (Cu-NP) on the enchytraeid Enchytraeus albidus is compared to the toxicity of a copper-salt (CuCl(2)). The effect parameters studied were
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