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Sigma-Aldrich

Poly(diallyldimethylammonium chloride) solution

average Mw 200,000-350,000 (medium molecular weight), 20 wt. % in H2O

Synonym(s):

PDADMAC

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About This Item

Linear Formula:
(C8H16ClN)n
CAS Number:
26062-79-3
MDL number:
MFCD00192409
UNSPSC Code:
12162002
NACRES:
NA.23

form

viscous liquid

mol wt

average Mw 200,000-350,000 (medium molecular weight)

concentration

20 wt. % in H2O

refractive index

n20/D 1.375

viscosity

250-500 cP(25 °C, Brookfield)

density

1.04 g/mL at 25 °C

InChI

1S/C8H16N.ClH/c1-5-7-9(3,4)8-6-2;/h5-6H,1-2,7-8H2,3-4H3;1H/q+1;/p-1

InChI key

GQOKIYDTHHZSCJ-UHFFFAOYSA-M

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General description

Poly(diallyldimethylammonium chloride) solution (PDADMAC) is a cationic polyelectrolyte prepared by the radical polymerization of diallyldimethylammonium chloride (DADMAC) in presence of a catalyst in the form of an organic peroxide. It is widely utilized as a flocculant.

Application

PDADMAC can be used as an electrolytic solution in a variety of applications such as drug delivery, biomedical systems, and sensors, which include biosensors and chemical sensors.

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis and solution properties of poly (N-isopropylacrylamide-co-diallyldimethylammonium chloride)
Deng Y and Pelton R
Macromolecules, 28(13), 4617-4621 (1995)
Polyelectrolyte multilayer as matrix for electrochemical deposition of gold clusters: toward super-hydrophobic surface
Zhang X, et al.
Journal of the American Chemical Society, 126(10), 3064-3065 (2004)
Lokesh S Koodlur
Bioelectrochemistry (Amsterdam, Netherlands), 91, 21-27 (2013-01-22)
A self-assembled molecular film of a water-soluble cobalt tetrasulfophthalocyanine was deposited on a gold substrate premodified with poly(diallyldimethylammonium chloride). The process of layer-by-layer assembly on the gold substrate was characterized using UV-Vis, Raman spectroscopy, ellipsometry, contact angle measurements, atomic force
Lulu Han et al.
Biomaterials, 34(4), 975-984 (2012-11-07)
The directional cell migration plays a crucial role in a variety of physiological and pathological processes. It can be controlled by the gradient cues immobilized on the substrate. The poly(sodium 4-styrenesulfonate) (PSS)/poly(diallyldimethylammonium) chloride (PDADMAC) multilayers were post-treated in a gradient
M M Ottakam Thotiyl et al.
Journal of colloid and interface science, 383(1), 130-139 (2012-07-20)
Multilayers of poly(diallyldimethylammonium chloride) (PDDA) and citrate capped Au nanoparticles (AuNPs) anchored on sodium 3-mercapto-1-propanesulfonate modified gold electrode by electrostatic layer-by-layer assembly (LbL) technique are shown to be an excellent architecture for the direct electrochemical oxidation of As(III) species. The
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Polyelectrolyte Multilayer Films and Membrane Functionalization

We present an article that discusses two applications in particular; first, using these layers as polyelectrolyte membranes to control permeability.

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