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308315

Sigma-Aldrich

Lithium hexafluoroarsenate(V)

greener alternative

98%

Synonym(s):

Hexafluoroarsenate(V) lithium

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About This Item

Linear Formula:
LiAsF6
CAS Number:
29935-35-1
Molecular Weight:
195.85
EC Number:
249-963-0
MDL number:
MFCD00011076
UNSPSC Code:
12352302
PubChem Substance ID:
24858666
NACRES:
NA.23

Assay

98%

form

powder

reaction suitability

reagent type: catalyst
core: arsenic

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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application(s)

battery manufacturing

greener alternative category

Enabling,

SMILES string

[Li+].F[As-](F)(F)(F)(F)F

InChI

1S/AsF6.Li/c2-1(3,4,5,6)7;/q-1;+1

InChI key

GTZQZEYBOGZTEO-UHFFFAOYSA-N

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General description

Lithium hexafluoroarsenate(V) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

The surface chemistry of Li electrodes in ethereal LiAsF6 was tested with new salts for potential battery systems.

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Statements

H301 + H331,H410

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ6116
MKCN0727
MKCL7755
MKCF1718
MKCG1095

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Ling-Yun Yang et al.
Angewandte Chemie (International ed. in English), 53(14), 3631-3635 (2014-03-07)
A new category of crystalline polymer electrolyte prepared by the supramolecular self-assembly of polyethylene oxide (PEO), α-cyclodextrin (α-CD), and LiAsF6 is reported. The polymer electrolyte consists of the nanochannels formed by α-CDs in which the PEO/Li(+) complexes are confined. The
The Li-ion rechargeable battery: a perspective
Goodenough JB and Park K
Journal of the American Chemical Society, 135(4), 1167-1176 (2013)
Electrodes with high power and high capacity for rechargeable lithium batteries
Kang K, et al.
Science, 311(5763), 977-980 (2006)
Challenges for rechargeable Li batteries
Goodenough JB and Kim Y
Chemistry of Materials, 22(3), 587-603 (2009)
Towards greener and more sustainable batteries for electrical energy storage
Larcher D and Tarascon J
Nature Chemistry, 7(1), 19-19 (2015)

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Research and development of solid-state lithium fast-ion conductors is crucial because they can be potentially used as solid electrolytes in all-solid-state batteries, which may solve the safety and energy-density related issues of conventional lithium-ion batteries that use liquid (farmable organic) electrolytes.

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