254274
Lithium hydroxide monohydrate
99.95% trace metals basis
Synonym(s):
Lithine hydrate
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All Photos(4)
About This Item
Linear Formula:
LiOH · H2O
CAS Number:
Molecular Weight:
41.96
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99.95% trace metals basis
form
crystalline
greener alternative product characteristics
Design for Energy Efficiency
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impurities
≤550.0 ppm Trace Metal Analysis
application(s)
battery manufacturing
greener alternative category
, Enabling
SMILES string
[Li+].O.[OH-]
InChI
1S/Li.2H2O/h;2*1H2/q+1;;/p-1
InChI key
GLXDVVHUTZTUQK-UHFFFAOYSA-M
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General description
Lithium hydroxide monohydrate is a strongly alkaline crystalline solid soluble in water. It is prepared industrially by recovering it from spodumene or by evaporating a solution prepared by reacting calcium hydroxide and lithium carbonate. It is mainly used in the synthesis of cathode materials for lithium-ion batteries, such as lithium cobalt oxide (LiCoO2) and lithium iron phosphate. It is also preferred over lithium carbonate for producing lithium nickel manganese cobalt oxides.
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Application
Lithium hydroxide monohydrate can be used mainly for the synthesis of cathode materials for Lithium-ion batteries:
- To synthesize Olivine LiFePO4 nanoplates with different crystal orientations by glycol-based solvothermal process. It demonstrated that the crystal orientation of cathode nanoplates plays an important role in the performance.
- As a precursor for the synthesis of LiFePO4 platelets under hydrothermal synthesis conditions. It exhibited homogeneous particle size distribution, greater electrochemical performances and cycle life, and morphology control.
- To synthesize Ni-rich Li[NixCoyMn1–x–y]O2 gradient cathodes (NCM). These cathodes exhibited enhanced cycling and chemical stability due to their strong crystallographic texture, unique particle morphology, and highly correlated particle orientation.
- As a precursor to prepare porous salt hydrate-based composites for low-temperature thermochemical heat storage.
- As an electrolyte additive in lithium-ion batteries.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
8B - Non-combustible, corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Viktoria V Sursyakova et al.
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Journal of chromatography. A, 1187(1-2), 188-196 (2008-02-29)
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Kwang-Heon Kim et al.
Ultrasonics sonochemistry, 15(6), 1019-1025 (2008-05-09)
Nano-sized HT-LiCoO(2) powders were prepared by sonochemical synthesis in an aqueous solution of lithium hydroxide containing cobalt hydroxide at approximately 80 degrees C without any further heat treatment at high temperature. The effects of the LiOH concentration, oxidation conditions, ultrasound
Hui-Ping Yi et al.
The Journal of organic chemistry, 72(3), 870-877 (2007-01-27)
Four intramolecular hydrogen bonding-driven aromatic amide foldamers 2-5 have been designed and synthesized in which a 2-methoxy-3-nitrobenzamide unit was incorporated at the end of the backbone. Kinetic studies in dioxane-water (4:1, v/v) at 60-90 degrees C have revealed that the
Timothy D Vaden et al.
Physical chemistry chemical physics : PCCP, 8(26), 3078-3082 (2006-06-29)
The internal energy or effective temperature of cluster ions has become an important issue in characterizing the structures observed in these species. This report considers the role played by the method of ion preparation (laser vaporization-supersonic expansion versus ion impact-evaporative
Articles
Lithium-ion batteries represent a group of electrochemical devices used for electricity storage and have attracted a lot of attention in the past two decades due to their portability, rechargeability and low cost.
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