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Perfluorobenzophenone

Name: Perfluorobenzophenone
Brand: ALDRICH

98%

Synonym(s):

Decafluorobenzophenone, Perfluorobenzophenone

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About This Item

Linear Formula:

C₆F₅COC₆F₅

CAS Number:

853-39-4

Molecular Weight:

362.12

Beilstein:

2066476

EC Number:

212-717-8

MDL number:

MFCD00000295

UNSPSC Code:

12352100

PubChem Substance ID:

24846557

NACRES:

NA.22

Assay

98%

form

solid

mp

90-95 °C (lit.)

SMILES string

Fc1c(F)c(F)c(c(F)c1F)C(=O)c2c(F)c(F)c(F)c(F)c2F

InChI

1S/C13F10O/c14-3-1(4(15)8(19)11(22)7(3)18)13(24)2-5(16)9(20)12(23)10(21)6(2)17

InChI key

WWQLXRAKBJVNCC-UHFFFAOYSA-N

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Application

Perfluorobenzophenone was used in the synthesis of fluorinated acridones and acridines.

Biochem/physiol Actions

Perfluorobenzophenone alcoholic solution generates ketyl and radical anion which can be studied by electron spin resonance spectra. Perfluorobenzophenone undergoes photolysis to form ketyl (C₆F₅⁾C^.OH radical.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The Electron Spin Resonance Spectra of the Photochemically Produced Perfluorobenzophenone Ketyl and Anion Radicals.

Sargent FP and Bailey MG.

Canadian Journal of Chemistry, 49(13), 2350-2352 (1971)

The Photochemically Produced Ketyl of Perfluorobenzophenone: Electron Spin Resonance Studies of Solvent Effects.

Sargent FP and Bailey MG.

Canadian Journal of Chemistry, 51(19), 3211-3216 (1973)

Orthogonal Synthesis of Fluorinated Acridones and Acridines from Perfluorobenzophenone.

Del Buttero P, et al

European Journal of Organic Chemistry, 2011(12), 2265-2271 (2011)

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