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Key Documents

ALD00612

(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide

≥95%

Synonym(s):

Yu MPAAM ligand

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About This Item

Empirical Formula (Hill Notation):
C13H20N2O
CAS Number:
Molecular Weight:
220.31
UNSPSC Code:
12352200
NACRES:
NA.22

Assay

≥95%

form

powder

reaction suitability

reaction type: C-C Bond Formation

storage temp.

−20°C

Application

(S)-N-(1-(Dimethylamino)-3-phenylpropan-2-yl)acetamide is an MPAAM ligand developed in the Yu Group for the Pd-catalyzed enantioselective C(sp3)-H arylation of fre cyclopropanecarboxylic and aminoisobutyric acids.

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Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Peng-Xiang Shen et al.
Journal of the American Chemical Society, 140(21), 6545-6549 (2018-05-10)
A monoprotected aminoethyl amine chiral ligand based on an ethylenediamine backbone was developed to achieve Pd-catalyzed enantioselective C(sp3)-H arylation of cyclopropanecarboxylic and 2-aminoisobutyric acids without using exogenous directing groups. This new chiral catalyst affords new disconnection for preparing diverse chiral

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