778583
Azidobenzene solution
~0.5 M in 2-methyltetrahydrofuran, ≥95.0% (HPLC)
Synonym(s):
Phenyl azide solution
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About This Item
Empirical Formula (Hill Notation):
C6H5N3
CAS Number:
Molecular Weight:
119.12
Beilstein:
742248
MDL number:
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥95.0% (HPLC)
form
liquid
greener alternative product characteristics
Catalysis
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sustainability
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concentration
~0.5 M in 2-methyltetrahydrofuran
impurities
≤2.0% water
greener alternative category
storage temp.
−20°C
SMILES string
[N-]=[N+]=Nc1ccccc1
InChI
1S/C6H5N3/c7-9-8-6-4-2-1-3-5-6/h1-5H
InChI key
CTRLRINCMYICJO-UHFFFAOYSA-N
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General description
Azidobenzene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Application
Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT RE 2
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
10.4 °F
Flash Point(C)
-12 °C
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3-Methyl-1-phenyltriazene and a series of ring-substituted derivatives (4-methylphenyl, 4-chlorophenyl, and 2,4,6-trichlorophenyl), structurally related benzenediazonium fluoborates and phenyl azides, as well as the recently isolated [1-methyl-3-(2,4,6-trichlorophenyl)-2-triazeno]methyl-beta-D-glucopyranoside uronic acid, were studied for their mutagenic activity in Salmonella typhimurium strains. Of these compounds
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 778583-10ML | 4061838076311 |
| 778583-50ML | 4061838111692 |
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