747793

(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆

• Synonym(s): [Ir{dF(CF₃)ppy}₂(dtbpy)]PF₆, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate
• Empirical Formula (Hill Notation): C₄₂H₃₄F₁₆IrN₄P
• CAS Number: 870987-63-6
• Molecular Weight: 1121.91
• UNSPSC Code: 12352300
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• reaction suitability: core: iridium; reagent type: catalyst; reaction type: Photocatalysis
• mp: >300 °C
• photocatalyst activation: 450 nm
• SMILES string: F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

Description

Application

(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆ is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable