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592552

Sigma-Aldrich

Pentabromophenyl acrylate

96%

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About This Item

Linear Formula:
Br5C6OCOCH=CH2
CAS Number:
52660-82-9
Molecular Weight:
542.64
MDL number:
MFCD00080604
UNSPSC Code:
12352103
PubChem Substance ID:
24881397
NACRES:
NA.23

Assay

96%

form

solid

mp

148-151 °C (lit.)

storage temp.

−20°C

SMILES string

Brc1c(Br)c(Br)c(OC(=O)C=C)c(Br)c1Br

InChI

1S/C9H3Br5O2/c1-2-3(15)16-9-7(13)5(11)4(10)6(12)8(9)14/h2H,1H2

InChI key

BKKVYNMMVYEBGR-UHFFFAOYSA-N

Application

Pentabromophenyl acrylate can form copolymers with acrylonitrile in aqueous emulsions or in the presence of a free radical initiator.

Other Notes

Monomer used to make high refractive index polymer for optical waveguides.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCK9870
11305TH
04003PD
16017MA

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Copolymers of acrylonitrile with some brominated acrylates.
Janovic Z, et al.
J. Macromol. Sci. Chem., 19(8-9), 1137-1152 (1983)
Olesya Daikos et al.
Physical chemistry chemical physics : PCCP, 18(47), 32369-32377 (2016-11-18)
Pentabrominated and fluorinated aromatic (meth)acrylates as well as their non-halogenated counterparts have been studied with the aim to avoid conventional photoinitiators and to overcome some negative consequences related to their use. Therefore, RTIR spectroscopy, laser flash photolysis and GC/MS were

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