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547816

Sigma-Aldrich

Tris[N,N-bis(trimethylsilyl)amide]europium(III)

98%

Synonym(s):

1,1,1-Trimethyl-N-(trimethylsilyl)silanamine europium salt

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About This Item

Linear Formula:
Eu(N(Si(CH3)3)2)3
CAS Number:
35789-02-7
Molecular Weight:
633.12
MDL number:
MFCD03411248
UNSPSC Code:
12352300
PubChem Substance ID:
24878982
NACRES:
NA.22

Assay

98%

form

solid

reaction suitability

core: europium
reagent type: catalyst

mp

147-154 °C (lit.)

SMILES string

C[Si](C)(C)N([Eu](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C

InChI

1S/3C6H18NSi2.Eu/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3

InChI key

FLADHQMJJLOUHM-UHFFFAOYSA-N

Application

Reactant for:
  • Preferential complexation reactions
  • Pin-wheel shaped heterobimetallis lanthanide alkali metal binaphtholates

Reactant for synthesis of:
  • Isostructural neo-pentoxide derivatives of Group 3 and lanthanide series metals for production of Ln2O3 nanoparticles
  • Anhydrous mononuclear tris(8-quinolinolato)lanthanoid complexes for organic light-emitting devices

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H228,H261,H314

Hazard Classifications

Flam. Sol. 1 - Skin Corr. 1B - Water-react 2

Supplementary Hazards

EUH014

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

36.0 °F - closed cup

Flash Point(C)

2.2 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCG8848
MKBL2760V
MKBK2928V
MKBJ8752V
16414CO

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Hung-Che Chou et al.
Colloids and surfaces. B, Biointerfaces, 73(2), 244-249 (2009-06-24)
This paper utilizes a silver electrode quartz crystal microbalance (QCM) mass sensor to detect the physiology of cells. This study also investigates the plasma surface modification of silver electrode QCMs through deposition of hexamethyldisilazane (HMDSZ) films as a protection film.
Nan Li et al.
Lab on a chip, 8(12), 2105-2112 (2008-11-22)
High-density live cell array serves as a valuable tool for the development of high-throughput immunophenotyping systems and cell-based biosensors. In this paper, we have, for the first time, demonstrated a simple fabrication process to form the hexamethyldisilazane (HMDS) and poly(ethylene
Tatsuya Nitabaru et al.
Journal of the American Chemical Society, 131(38), 13860-13869 (2009-09-10)
Full details of an anti-selective catalytic asymmetric nitroaldol reaction promoted by a heterobimetallic catalyst comprised of Nd(5)O(O(i)Pr)(13), an amide-based ligand, and NaHMDS (sodium hexamethyldisilazide) are described. A systematic synthesis and evaluation of amide-based ligands led to the identification of optimum
Nondestructively creating nanojunctions by combined-dynamic-mode dip-pen nanolithography.
Guanxia Shen et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 10(13), 2226-2229 (2009-07-16)
Juliana Tsz Yan Lee et al.
Scanning, 34(1), 12-25 (2012-04-26)
Common dehydration methods of cells on biomaterials for scanning electron microscopy (SEM) include air drying, hexamethyldisilazane (HMDS) or tetramethysilane (TMS) treatment and critical point drying (CPD). On the other side, freeze-drying has been widely employed in dehydrating biological samples and
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