338001

Zirconium(IV) acetylacetonate

97%

• Synonym(s): 2,4-Pentanedione zirconium(IV) derivative, Tetrakis(2,4-pentanedionato)zirconium(IV), Zirconium(IV) 2,4-pentanedionate
• Linear Formula: Zr(C₅H₇O₂)₄
• CAS Number: 17501-44-9
• Molecular Weight: 487.66
• Beilstein: 4160373
• EC Number: 241-510-5
• MDL number: MFCD00000036
• UNSPSC Code: 12352103
• PubChem Substance ID: 24860510
• NACRES: NA.23

Properties

• Quality Level: 200
• Assay: 97%
• form: powder
• reaction suitability: core: zirconium; reagent type: catalyst
• SMILES string: CC(=O)\C=C(\C)O[Zr](O\C(C)=C/C(C)=O)(O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O
• InChI: 1S/4C5H8O2.Zr/c4*1-4(6)3-5(2)7;/h4*3,6H,1-2H3;/q;;;;+4/p-4/b4*4-3-;
• InChI key: FPFOSIXCIBGKOH-MTOQALJVSA-J

Description

General description

Zirconium(IV) acetylacetonate is a white crystalline organometallic solid widely used as a sol-gel precursor to synthesize Zirconium-based nanomaterials and thin films. It also finds application in the field of catalysis and polymer synthesis.

Application

Zirconium(IV) acetylacetonate can be used:

• As a sol-gel precursor to synthesize zirconia nanoparticles with photocatalytic activity.
• As an additive to improve the performance of the electron transport layer in perovskite solar cells.
• To synthesize as-prepared zirconium acetylacetonate (a-ZrAcac) film as a cathode buffer layer in polymer solar cells. It exhibited an average power conversion efficiency (PCE) of 8.75% which is significantly improved than that of the devices with traditional Ca/Al cathode.
• To synthesize high-κ zirconium oxide gate dielectric for Organic Field-Effect Transistors at low voltage operation.
• To fabricate the conductive interlayers for quantum dot light-emitting devices(QLEDs), which enhances quantum efficiency, power efficiency, and longer operational lifetimes.
• As a ring-opening initiator to synthesize biodegradable polyacids.
• As a catalyst to synthesize polylactide terpolymers.

Safety Information

• Pictograms: GHS02,GHS07
• Signal Word: Danger
• Hazard Statements: H228,H302
• Precautionary Statements: P210 - P240 - P241 - P264 - P280 - P301 + P312
• Hazard Classifications: Acute Tox. 4 Oral - Flam. Sol. 1
• Storage Class Code: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves