270245
4-Methoxybenzyl chloride
contains potassium carbonate as stabilizer, 98%
Synonym(s):
4-(Chloromethyl)anisole
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About This Item
Linear Formula:
CH3OC6H4CH2Cl
CAS Number:
Molecular Weight:
156.61
Beilstein:
606667
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
form
liquid
contains
potassium carbonate as stabilizer
refractive index
n20/D 1.548 (lit.)
bp
117-118 °C/14 mmHg (lit.)
mp
−1 °C (lit.)
density
1.155 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
COc1ccc(CCl)cc1
InChI
1S/C8H9ClO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6H2,1H3
InChI key
MOHYOXXOKFQHDC-UHFFFAOYSA-N
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General description
4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.
Application
4-Methoxybenzyl chloride was used to benzylate the aniline nitrogen. It was also used in the synthesis of 1-naphthamide and diarymethanes via Suzuki cross-coupling with postassium aryltrifluoroborates.
O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
228.2 °F - closed cup
Flash Point(C)
109 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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