256781
Diethylzinc
≥52 wt. % Zn basis
Synonym(s):
DEZn, Et2Zn, DEZ, Zincdiethyl
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About This Item
Linear Formula:
(C2H5)2Zn
CAS Number:
Molecular Weight:
123.51
Beilstein:
3587207
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
form
liquid
concentration
≥52 wt. % Zn
refractive index
n20/D 1.498 (lit.)
bp
117 °C (lit.)
mp
−28 °C (lit.)
density
1.205 g/mL at 25 °C (lit.)
SMILES string
CC[Zn]CC
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
InChI key
HQWPLXHWEZZGKY-UHFFFAOYSA-N
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Application
Diethylzinc has been used as a zinc precursor for the synthesis of colloidal Cu/Zn-based nanoparticles, and zinc on silica catalysts via atomic layer deposition (ALD) technique.
Packaging
Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.
Compatible with the following:
Compatible with the following:
- Aldrich® Sure/Pac™ station for liquefied gases Z566446
- PTFE Sealing tape Z104388 or Z221880
- Straight septum-inlet adapter Z118141 with septa Z565687 or Z565695
Legal Information
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
also commonly purchased with this product
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Description
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recommended
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septum inlet adapter
Product No.
Description
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react 1
Supplementary Hazards
Storage Class Code
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Bifunctional catalysts based on colloidal Cu/Zn nanoparticles for the direct conversion of synthesis gas to dimethyl ether and hydrocarbons
Gentzen, M and Doronkin, DE and Sheppard, TL and Grunwaldt, J-D and Sauer, J and Behrens, S
Applied Catalysis A: General, 557, 99-107 (2018)
Bifunctional hybrid catalysts derived from Cu/Zn-based nanoparticles for single-step dimethyl ether synthesis
Gentzen, M and Habicht, W and Doronkin, DE and Grunwaldt, J-D and Sauer, J and Behrens, S
Catalysis Science & Technology, 6(4), 1054-1063 (2016)
Single-site zinc on silica catalysts for propylene hydrogenation and propane dehydrogenation: Synthesis and reactivity evaluation using an integrated atomic layer deposition-catalysis instrument
Camacho-Bunquin J, et al.
J. Catal., 345, 170-182 (2017)
Sang-Jin Jeon et al.
Journal of the American Chemical Society, 127(47), 16416-16425 (2005-11-25)
There is a great demand for development of catalyst systems that are not only efficient and highly enantioselective but are also environmentally benign. Herein we report investigations into the catalytic asymmetric addition of alkyl and functionalized alkyl groups to ketones
Lianbing Zhang et al.
Angewandte Chemie (International ed. in English), 48(27), 4982-4985 (2009-06-06)
New uses for ALD: By applying standard metal oxide atomic layer deposition (ALD) to two types of porphyrins, site-specific chemical infiltration of substrate molecules is achieved: Diethylzinc can diffuse into the interior of porphyrin supramolecular structures and induce metalation of
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