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230227

Sigma-Aldrich

Tris(4-bromophenyl)ammoniumyl hexachloroantimonate

technical grade

Synonym(s):

Hexachloroantimonate tris(4-bromophenyl)amine, Magic Blue, Tris(4-bromophenyl)aminium hexachloroantimonate, Tris(p-bromophenyl)aminium hexachloroantimonate(1-), Tris(p-bromophenyl)aminium hexachloroantimonate

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About This Item

Linear Formula:
(BrC6H4)3NSbCl6
CAS Number:
Molecular Weight:
816.48
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

form

powder

mp

142 °C (dec.) (lit.)

SMILES string

Cl[Sb-](Cl)(Cl)(Cl)(Cl)Cl.Brc1ccc(cc1)[N+](c2ccc(Br)cc2)c3ccc(Br)cc3

InChI

1S/C18H12Br3N.6ClH.Sb/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18;;;;;;;/h1-12H;6*1H;/q+1;;;;;;;+5/p-6

InChI key

SDHBPVANTRLAKE-UHFFFAOYSA-H

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Application

Tris(4-bromophenyl)ammoniumyl hexachloroantimonate can be used as a strong oxidant for the chemical doping of conjugated polymers. It can also be used as a catalyst for the deprotection of tert-butyldimethylsilyl and tetrahydropyranyl ethers.

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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A mild and efficient cleavage of tert-butyldimethylsilyl (TBS) and tetrahydropyranyl (THP) ethers using a catalytic amount of TBPA+ SbCl6
Xu Y, et al.
Tetrahedron Letters, 49, 3634-3637 (2008)
Chemical doping of conjugated polymers with the strong oxidant magic blue
Hofmann A, et al.
Advanced Electronic Materials, 6, 2000249-2000249 (2020)

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