109231
3-Bromopropionitrile
≥98.0% (GC)
Synonym(s):
3-Bromopropanenitrile
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About This Item
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Assay
≥98.0% (GC)
refractive index
n20/D 1.481 (lit.)
bp
76-78 °C/10 mmHg (lit.)
density
1.615 g/mL at 25 °C (lit.)
functional group
bromo
SMILES string
BrCCC#N
InChI
1S/C3H4BrN/c4-2-1-3-5/h1-2H2
InChI key
CQZIEDXCLQOOEH-UHFFFAOYSA-N
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Application
3-Bromopropionitrile was used as the initiator in the atom transfer radical polymerization of acrylonitrile. 3-Bromopropionitrile was used in coupling reactions of a number of aromatic and heteroaromatic phenols with alkyl, acyl or benzoyl halides in acetonitrile with cesium fluoride-Celite.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Oral
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
206.6 °F - closed cup
Flash Point(C)
97 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Preparation of polyacrylonitrile with improved isotacticity and low polydispersity.
Journal of Applied Polymer Science, 116(5), 2610-2616 (2010)
Cesium fluoride-Celite: a solid base for efficient syntheses of aromatic esters and ethers.
Tetrahedron, 61(27), 6652-6656 (2005)
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