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Key Documents

ALD00484

Sigma-Aldrich

Sodium 7-Chloro-1,1-difluoroheptane-1-sulfinate

contains ≤15% sodium 7-(ethylthio)-1,1-difluoroheptane-1-sulfinate

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About This Item

Empirical Formula (Hill Notation):
C7H12ClF2NaO2S
Molecular Weight:
256.67
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

form

powder

Quality Level

contains

≤15% sodium 7-(ethylthio)-1,1-difluoroheptane-1-sulfinate

reaction suitability

reaction type: C-C Bond Formation
reaction type: C-H Activation
reagent type: catalyst

mp

185 °C

SMILES string

O=S(C(F)(F)CCCCCCCl)O[Na]

InChI

1S/C7H13ClF2O2S.Na/c8-6-4-2-1-3-5-7(9,10)13(11)12;/h1-6H2,(H,11,12);/q;+1/p-1

InChI key

LFIQXRUQAPPIPD-UHFFFAOYSA-M

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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