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87993

Sigma-Aldrich

Tetraoctylammonium hydroxide solution

~20% in methanol (T)

Synonym(s):

Tetra-N-octyl ammonium hydroxide

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About This Item

Linear Formula:
[CH3(CH2)7]4N(OH)
CAS Number:
Molecular Weight:
483.90
Beilstein:
7323584
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

concentration

~20% in methanol (T)

anion traces

bromide (Br-): ≤500 mg/kg

storage temp.

2-8°C

SMILES string

[OH-].CCCCCCCC[N+](CCCCCCCC)(CCCCCCCC)CCCCCCCC

InChI

1S/C32H68N.H2O/c1-5-9-13-17-21-25-29-33(30-26-22-18-14-10-6-2,31-27-23-19-15-11-7-3)32-28-24-20-16-12-8-4;/h5-32H2,1-4H3;1H2/q+1;/p-1

InChI key

DCFYRBLFVWYBIJ-UHFFFAOYSA-M

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Application

Tetraoctylammonium hydroxide solution can be used as:
  • A lipophilic base in the study of its effect on optical pCO2 sensors.
  • A lipophilic organic base in the preparation of nanobeads, which are used as sensors for the detection of acidic and basic gases.
  • A starting material for the preparation of ionic liquid named tetraoctylammonium 2-methyl-1-naphthoate, which is used in the extraction of 2,3-butanediol from H2O.

Other Notes

Very lipophilic phase-transfer agent; employed in a carbon dioxide optical sensor

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 1

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

51.8 °F - closed cup

Flash Point(C)

11 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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The influence of the lipophilic base in solid state optical pCO2 sensors
Schroder CR and Klimant I
Sensors and Actuators B, Chemical, 107(2), 572-579 (2005)
A. Mills et al.
Analytical Chemistry, 64, 1383-1383 (1992)
Precipitation as a simple and versatile method for preparation of optical nanochemosensors
Borisov SM, et al.
Talanta, 79(5), 1322-1330 (2009)

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