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796557

Sigma-Aldrich

Stahl Aerobic Oxidation ABNO solution

0.04M ABNO in Acetonitrile, Solution for Oxidation of Primary and Secondary Alcohols

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About This Item

UNSPSC Code:
12352000
NACRES:
NA.22

description

Freezing Point: 44.6°F

form

liquid

reaction suitability

reagent type: oxidant

refractive index

n/D 1.357

density

0.796 at 25 °C

storage temp.

2-8°C

General description

Stahl Aerobic Oxidation ABNO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and ABNO for the oxidation of primary and secondary alcohols.

Application

This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

43.5 °F

Flash Point(C)

6.38 °C


Certificates of Analysis (COA)

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Articles

Alcohol oxidation is one of the most frequently performed oxidation reactions in organic chemistry. The aldehyde and ketone products of alcohol oxidation are useful intermediates en route to complex molecules.

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