763896
DL-α-Tocopherol methoxypolyethylene glycol succinate
Synonym(s):
Polyethylene glycol, TPGS-750-M
About This Item
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form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: C-H Activation
reagent type: surfactant
greener alternative product characteristics
Catalysis
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transition temp
Tm 29-34
greener alternative category
, Aligned
General description
Application
TPGS-750-M can also be employed in:
- The nucleophilic aromatic substitution reaction of aryl and heteroaryl halides with nitrogen, oxygen, and sulfur nucleophiles under mild conditions.
- The preparation of quinoxaline-2,3 diones from quinoxalinones via C(sp2)-H hydroxylation reaction.
- The intramolecular N-arylation of amines using a copper catalyst.
Other Notes
From milligrams to kilograms: synthetic chemistry following nature′s lead
related product
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Articles
Lipshutz and co-workers have recently developed a second generation technology to their original PTS-enabling surfactant based on the polyoxyethanyl-α-tocopheryl succinate derivative, TPGS-750-M.
TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.
Protocols
TPGS-750-M, a second generation surfactant, may be used for Suzuki-Miyaura Reactions in Water at Room Temperature
Buchwald-Hartwig Amination Reaction in Water at Room Temperature using TPGS-750-M
Related Content
Micellular catalysis has provided the ability to carry out several commonly used transformations used in the synthetic community to be carried out in water.
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