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723037

Sigma-Aldrich

2-Cyano-2-propyl dodecyl trithiocarbonate

97% (HPLC)

Synonym(s):

S-(2-Cyanoprop-2-yl)-S-dodecyltrithiocarbonate

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About This Item

Empirical Formula (Hill Notation):
C17H31NS3
CAS Number:
870196-83-1
Molecular Weight:
345.63
MDL number:
MFCD11973800
UNSPSC Code:
12352100
PubChem Substance ID:
329763970
NACRES:
NA.23

Quality Level

100

Assay

97% (HPLC)

form

liquid

refractive index

n20/D 1.535

density

0.991 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCCSC(=S)SC(C)(C)C#N

InChI

1S/C17H31NS3/c1-4-5-6-7-8-9-10-11-12-13-14-20-16(19)21-17(2,3)15-18/h4-14H2,1-3H3

InChI key

QSVOWVXHKOQYIP-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
2-Cyano-2-propyl dodecyl trithiocarbonate is used as a RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylate, methacrylamide, and styrene monomers. It is also used as a Chain Transfer Agent (CTA).

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM5629
MKCJ2182
MKCJ1879
MKCJ1880
MKCJ2181

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Jeonghun Lee et al.
Journal of controlled release : official journal of the Controlled Release Society, 304, 164-172 (2019-05-15)
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Matías Regiart et al.
Analytica chimica acta, 963, 83-92 (2017-03-25)
We report a hybrid glass-poly (dimethylsiloxane) microfluidic immunosensor for epidermal growth factor receptor (EGFR) determination, based on the covalent immobilization of anti-EGFR antibody (anti-EGFR) on amino-functionalized mesoporous silica (AMS) retained in the central channel of a microfluidic device. The synthetized
Liqin Mei et al.
Journal of materials chemistry. B, 8(25), 5434-5440 (2020-06-13)
Zwitterionic polymers have attracted increasing attention due to their excellent fouling resistance ability and eco-friendliness. Yet, their non-degradability and hydrophilic nature limit their applications. In this study, we have prepared a novel surface-fragmenting hyperbranched copolymer with tertiary carboxybetaine ester (TCB)
Hsiu-Pen Lin et al.
Macromolecular bioscience, 20(6), e2000049-e2000049 (2020-04-08)
Cationic polymers exhibit high cytotoxicity via strong interaction with cell membranes. To reduce cell membrane damage, a hydrophilic polymer is introduced to the cationic nanoparticle surface. The hydrophilic polymer coating of cationic nanoparticles resulted in a nearly neutral nanoparticle. These
So Jung Park et al.
ACS applied materials & interfaces, 12(43), 49165-49173 (2020-09-30)
Control of the cross-linking reaction is imperative when developing a sophisticated in situ forming hydrogel in the body. In this study, a heteroarmed thermoresponsive (TR) nanoparticle was designed to investigate the mechanism of controlling reactivity of the functional groups introduced
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Articles

Evaluation of RAFT Agents

A series of polymerization were carried out using RAFT agents and monomers yielding well-defined polymers with narrow molecular weight distributions.

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

RAFT (Reversible Addition Fragmentation chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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Protocols

RAFT Polymerization Procedures

RAFT (Reversible Addition-Fragmentation chain Transfer) is a form of living radical polymerization involving conventional free radical polymerization of a substituted monomer in the presence of a suitable chain transfer (RAFT) reagent.

Concepts and Tools for RAFT Polymerization

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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