55262
4-[4-(1-Hydroxyethyl)-2-methoxy-5-nitrophenoxy]butyric acid
≥98.0% (HPLC), for peptide synthesis
Synonym(s):
Hydroxyethyl photolinker
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About This Item
Empirical Formula (Hill Notation):
C13H17NO7
CAS Number:
Molecular Weight:
299.28
Beilstein:
7717635
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.22
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product name
4-[4-(1-Hydroxyethyl)-2-methoxy-5-nitrophenoxy]butyric acid, ≥98.0% (HPLC)
Assay
≥98.0% (HPLC)
form
powder
reaction suitability
reagent type: cross-linking reagent
mp
163-166 °C
SMILES string
COc1cc(C(C)O)c(cc1OCCCC(O)=O)[N+]([O-])=O
InChI
1S/C13H17NO7/c1-8(15)9-6-11(20-2)12(7-10(9)14(18)19)21-5-3-4-13(16)17/h6-8,15H,3-5H2,1-2H3,(H,16,17)
InChI key
DUIJUTBRRZCWRD-UHFFFAOYSA-N
Other Notes
Photolabile linker which can be bound to amino- and hydroxymethyl resins. Synthesis of sensitive acids
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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D.L. Whitehouse et a
Tetrahedron Letters, 38, 7851-7851 (1997)
Christopher P. Holmes
The Journal of organic chemistry, 62(8), 2370-2380 (1997-04-18)
Both a model phenacyl and o-nitrobenzyl photolabile linker from the literature along with four new o-nitrobenzyl linkers were prepared and the kinetics of their photolytic cleavage examined in solution. The linkers were prepared by amidation of the carboxylic acid anchoring
Mime Kobayashi et al.
Journal of biomaterials science. Polymer edition, 30(13), 1161-1171 (2019-06-16)
We have developed biocompatible scaffolds that enable cell fate control with visible light. The scaffolds are based on synthetic collagen-like polypeptide, poly(prolyl-hydroxyprolyl-glycyl) {poly(Pro-Hyp-Gly)} which has been used for cosmetics and other healthcare applications. Bioactive peptides were conjugated to the scaffolds
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