Skip to Content
Merck
All Photos(2)

Key Documents

451649

Sigma-Aldrich

Iron(III) chloride

greener alternative

anhydrous, powder, ≥99.99% trace metals basis

Synonym(s):

Ferric chloride, Iron trichloride, Molysite

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
FeCl3
CAS Number:
Molecular Weight:
162.20
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

Assay

≥99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: iron

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤100.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

Looking for similar products? Visit Product Comparison Guide

General description

Iron(III) chloride is brownish to black crystalline solid that is highly soluble in water. As a moderately strong Lewis acid, it highly reactive with bases and capable of forming complex ions. It is widely used as a iron precursor in the field of catalysis, solar cells and batteries.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride can be used:
  • As a precursor to fabricate nano-sized Fe-N-C catalysts for proton exchange membrane(PEM) fuel cells. FeCl3 iron precursor, helps to achieve the lowest charge transfer resistance and high peak power density.
  • As an oxidant to prepare FeOCl@PPy cathode materials for Li-ion batteries with good cycling stability.
  • As a precursor to fabricate amorphous multifunctional am-Fe–Bi/NF electrode for rechargeable Zinc-air batteries.
  • To synthesize Fe3O4@nanocellulose/TiCl nano fillers for dye-sensitized solar cells to reduce the crystallinity of the polymer.

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

accessory

Product No.
Description
Pricing

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Enhancing graphene/CNT based electrochemical detection using magneto-nanobioprobes.
Jiang M, et al.
Material Matters, 2, 877-883 (2012)
Priyanka Sharma et al.
Scientific reports, 2, 877-877 (2012-11-21)
Graphene and related materials have come to the forefront of research in electrochemical sensors during recent years due to the promising properties of these nanomaterials. Further applications of these nanomaterials have been hampered by insufficient sensitivity offered by these nanohybrids
Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was

Articles

Noble-Metal Nanostructures with Controlled Morphologies

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

Lithium-Ion Battery Performance: Dependence on Material Synthesis and Post‑Treatment Methods

We presents an article about a micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization. RAFT (Reversible Addition/Fragmentation Chain Transfer) polymerization is a reversible deactivation radical polymerization (RDRP) and one of the more versatile methods for providing living characteristics to radical polymerization.

See All

Protocols

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Sigma-Aldrich presents an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service