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310069

Sigma-Aldrich

Iron(II,III) oxide

powder, <5 μm, 95%

Synonym(s):

Ferrosoferric oxide, Iron oxide black, Magnetite

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About This Item

Empirical Formula (Hill Notation):
Fe3O4
CAS Number:
1317-61-9
Molecular Weight:
231.53
EC Number:
215-277-5
MDL number:
MFCD00011010
UNSPSC Code:
12352303
PubChem Substance ID:
24858770
NACRES:
NA.23

Quality Level

200

Assay

95%

form

powder

particle size

<5 μm

mp

1538 °C (lit.)

density

4.8-5.1 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

SMILES string

O=[Fe].O=[Fe]O[Fe]=O

InChI

1S/3Fe.4O

InChI key

SZVJSHCCFOBDDC-UHFFFAOYSA-N

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General description

Iron(II,III) oxide is an earth-abundant magneticoxide that has a high specific surface area, and good dispersion. The presenceof Fe3+ and Fe2+ with equal numbers in the Fe3O4structure provides higher light absorption and as a result superiorelectrocatalytic activities and high performance in solar cells compared toother iron oxides.

Application

Iron(II,III) oxide can be used as:
  • A starting material to synthesize Ca2Fe2O5 (srebrodolskite) microspheres via a single-stage flame spheroidisation (FS) process.
  • A catalyst for reverse water gas shift reactions(RWGS).

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP3084
MKCM2969
MKCL2153
MKCH9933
MKCH5599

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Miloch Marjanovic et al.
Water research, 140, 220-231 (2018-05-02)
In this work, solar disinfection (SODIS) was enhanced by moderate addition of Fe and sodium peroxydisulfate (PDS), under solar light. A systematic assessment of the activating factors was performed, firstly isolated, then in pairs and concluded in the combined Fe/heat/solar
Jens Baumgartner et al.
Nature materials, 12(4), 310-314 (2013-02-05)
The formation of crystalline materials from solution is usually described by the nucleation and growth theory, where atoms or molecules are assumed to assemble directly from solution. For numerous systems, the formation of the thermodynamically stable crystalline phase is additionally
Marina I Siponen et al.
Nature, 502(7473), 681-684 (2013-10-08)
Magnetotactic bacteria align along the Earth's magnetic field using an organelle called the magnetosome, a biomineralized magnetite (Fe(II)Fe(III)2O4) or greigite (Fe(II)Fe(III)2S4) crystal embedded in a lipid vesicle. Although the need for both iron(II) and iron(III) is clear, little is known
Maoquan Chu et al.
Biomaterials, 34(16), 4078-4088 (2013-03-08)
The photothermal effect of Fe3O4 magnetic nanoparticles is investigated for cancer therapy both in vitro and in vivo experiments. Heat is found to be rapidly generated by red and near-infrared (NIR) range laser irradiation of Fe3O4 nanoparticles with spherical, hexagonal and wire-like
Tsung-Ju Li et al.
Biomaterials, 34(32), 7873-7883 (2013-07-24)
We present an approach for synchronizing hyperthermia and thermal-responsive local drug release. The targeting probe has a magnetite nanocrystal (Fe₃O₄@PSMA) core and a polynucleotide shell that carries 5-fluorouracil (5-FU) and anti-human epidermal growth factor receptor 2 (anti-HER2) antibody for cancer
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Articles

Synthesis of Magnetic Nanoparticles for Biosensing

Professor Randal Lee (University of Houston, USA) discusses design considerations for iron oxide magnetic nanospheres and nanocubes used for biosensing, including synthetic procedures, size, and shape. The effects of these variables are discussed for various volumetric-based and surface-based detection schemes.

Self-Propagating Reactions Induced by Mechanical Alloying

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

Vistas in Current Magnetic Materials Research

Magnetism and magnetic materials have been of scientific interest for over 1,000 years. More recently, fundamental investigations have focused on exploring the various types of magnetic materials and understanding the magnetic effects created by electric currents.

Soft Magnetic Nanocrystalline Alloys: Materials and Models

Magnetic materials permeate numerous daily activities in our lives. They are essential components of a diversity of products including hard drives that reliably store information on our computers, decorative magnets that keep the shopping list attached to the refrigerator door, electric bicycles that speed our commute to work, as well as wind turbines for conversion of wind energy to electrical power.

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