223670
Bis(cyclopentadienyl)zirconium(IV) chloride hydride
95%
Synonym(s):
Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz’ reagent, Zirconocene chloride hydride
About This Item
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Assay
95%
form
powder
reaction suitability
core: zirconium
reagent type: catalyst
reagent type: reductant
SMILES string
[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
InChI key
PSYHEBZUPSHSKK-UHFFFAOYSA-M
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General description
Application
- To convert amides to aldehydes.
- As a reagent for the functionalization of olefins and alkynes.
- As a reducing agent in the preparation of (E)-vinyl organochalcogenides.
- To prepare a dioxaborolane derivative, which is a key intermediate for the synthesis of bridged-nicotine analogs.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B - Water-react 2
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
Personal Protective Equipment
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