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207918

Sigma-Aldrich

Europium(III) nitrate pentahydrate

99.9% trace metals basis

Synonym(s):

Europium trinitrate hydrate

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About This Item

Linear Formula:
Eu(NO3)3 · 5H2O
CAS Number:
Molecular Weight:
428.06
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.9% trace metals basis

form

crystals and lumps

reaction suitability

reagent type: catalyst
core: europium

impurities

≤1500.0 ppm Trace Rare Earth Analysis

SMILES string

O.O.O.O.O.[Eu+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Eu.3NO3.5H2O/c;3*2-1(3)4;;;;;/h;;;;5*1H2/q+3;3*-1;;;;;

InChI key

BBGDGFQCQRFYCP-UHFFFAOYSA-N

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General description

Europium(III) nitrate pentahydrate is a white crystalline solid with luminescent properties. It is widely used as a precursor to fabricate nanomaterials and perovskite solar cells.

Application

Europium(III) nitrate pentahydrate can be used:
  • As a precursor to synthesize Y2O3:Eu3+ thin-film phosphors by sol-gel method for display applications.
  • As a dopant to prepare crystalline nanophosphors. These are suitable for bioimaging as they are hydrophilic in nature and white light-emitting diodes.
  • To fabricate dye-sensitized solar cells with enhanced light-harvesting efficiency.
  • As a dopant to prepare various metal oxide nanoparticles, for example, ZnO nanoparticles for photocatalytic application.

Pictograms

Flame over circleExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Anıl İncel et al.
ACS applied materials & interfaces, 9(7), 6488-6496 (2017-01-27)
Lanthanide-based organometallic materials are well-known candidate triboluminescent (TL) materials that can show bright emission when a mechanical force is applied. These materials are usually in the form of crystalline powders, and it is often useful to integrate these samples into
Mariano Laguna et al.
Dalton transactions (Cambridge, England : 2003), 46(35), 11575-11583 (2017-08-08)
Uniform Eu-doped NaGd(WO
Sonika Kadyan et al.
Luminescence : the journal of biological and chemical luminescence, 35(5), 673-683 (2020-01-23)
The solution combustion technique was used to synthesize MLaAl3 O7 (M = Ba, Ca, Mg, and Sr) nanophosphors-doped with Eu3+ using metal nitrates as precursors. The photoluminescence (PL) emission spectra exhibited three peaks at 587-591, 610-616, and 653-654 corresponding to
Annealing and doping effects on the structure of europium-doped HfO 2 sol-gel material.
Villanueva-Iba?ez M,et al.
Opt. Mater., 24(1), 51-57 (2003)
Structural and luminescence properties of europium (III)-doped zirconium carbonates and silica-supported Eu3+-doped zirconium carbonate nanoparticles
Sivestrini S, et al.
Journal of Nanoparticle Research, 12(3), 993-1002 (2010)

Articles

Spectral conversion for solar cells is an emerging concept in the field of photovoltaics, and it has the potential to increase significantly the efficiency of solar cells. Lanthanide ions are ideal candidates for spectral conversion, due to their high luminescence efficiencies and rich energy level structure that allows for great flexibility in the upconversion and downconversion of photons in a wide spectral region (NIR-VIS-UV).

The rare earth elements impact nearly everyone in the world. All of the people living in advanced technological countries and almost all those living in third world countries utilize the rare earths in their everyday living—the car that one drives (gasoline is refined from oil using rare earth catalysts and catalytic converters reduce the polluting emissions from the automotive exhaust), watching the news on TV (the red and green colors in TV screens), the telephones and computers we use to communicate (the permanent magnets in speakers and disc drives), just to name a few examples.

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