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202126

Sigma-Aldrich

Cesium carbonate

99.9% trace metals basis

Synonym(s):

Carbonic acid dicesium

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About This Item

Linear Formula:
Cs2CO3
CAS Number:
534-17-8
Molecular Weight:
325.82
Beilstein:
4546405
EC Number:
208-591-9
MDL number:
MFCD00010957
UNSPSC Code:
12352301
PubChem Substance ID:
24852040
NACRES:
NA.22

Quality Level

200

Assay

99.9% trace metals basis

mp

610 °C (dec.) (lit.)

SMILES string

[Cs+].[Cs+].[O-]C([O-])=O

InChI

1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

FJDQFPXHSGXQBY-UHFFFAOYSA-L

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Application

Catalyst for:
Aerobic oxidation of primary alcohols
1,4-addition reactions

Reagent for:
Synthesis of phosphazene derivatives
Constrictive binding interactions
Intramolecular C-N cross coupling reactions
Dehydrohalogenative polycondensation reactions
Promotes the efficient O-alkylation of alcohols to form mixed alkyl carbonates.

Pictograms

Health hazardCorrosion
GHS08,GHS05

Signal Word

Danger

Hazard Statements

H318,H361f,H373

Hazard Classifications

Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral

Target Organs

Kidney,Adrenal gland,Testes

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCC8907
MKCC1688
MKBZ7000V
MKBZ2431V
MKBX4058V

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Erin M Sanehira et al.
Science advances, 3(10), eaao4204-eaao4204 (2017-11-04)
We developed lead halide perovskite quantum dot (QD) films with tuned surface chemistry based on A-site cation halide salt (AX) treatments. QD perovskites offer colloidal synthesis and processing using industrially friendly solvents, which decouples grain growth from film deposition, and
Chengxi Zhang et al.
Beilstein journal of nanotechnology, 8, 2521-2529 (2017-12-21)
Colloidal perovskite nanocrystals comprised of all inorganic cesium lead halide (CsPbX
Ming Liu et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 4(11), 1700335-1700335 (2017-12-05)
Bright and stable blue emitters with narrow full-width at half-maxima are particularly desirable for applications in television displays and related technologies. Here, this study shows that doping aluminum (Al
Daniel Amgar et al.
Nano letters, 17(2), 1007-1013 (2017-01-18)
Perovskite nanostructures, both hybrid organo-metal and fully inorganic perovskites, have gained a lot of interest in the past few years for their intriguing optical properties in the visible region. We report on inorganic cesium lead bromide (CsPbBr
Michael A Becker et al.
Nature, 553(7687), 189-193 (2018-01-13)
Nanostructured semiconductors emit light from electronic states known as excitons. For organic materials, Hund's rules state that the lowest-energy exciton is a poorly emitting triplet state. For inorganic semiconductors, similar rules predict an analogue of this triplet state known as
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Scale-Up Guide: Buchwald-Hartwig Amination Reaction

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

Scale-Up Guide: Buchwald-Hartwig Amination Reaction

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form. Once activated by base under the reaction conditions they become sensitive to air. To best enable scale-up success, the use of standard Schlenk technique is recommended.

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