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About This Item
Empirical Formula (Hill Notation):
C12H9N3
CAS Number:
Molecular Weight:
195.22
EC Number:
MDL number:
UNSPSC Code:
12352100
eCl@ss:
32151902
PubChem Substance ID:
NACRES:
NA.22
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Assay
97%
form
solid
mp
218-220 °C (lit.)
SMILES string
c1ccc(nc1)-c2nc3ccccc3[nH]2
InChI
1S/C12H9N3/c1-2-6-10-9(5-1)14-12(15-10)11-7-3-4-8-13-11/h1-8H,(H,14,15)
InChI key
YNFBMDWHEHETJW-UHFFFAOYSA-N
Application
2-(2-Pyridyl)benzimidazole was used as a chelating fluorescent ligand in the synthesis of cobalt(II) complex. It was also used in the preparation of (H(2)L(1))(2)[Ru(III)Cl(4)(CH(3)CN)(2)](2)[Ru(IV)Cl(4)(CH(3)CN)(2)]·2Cl·6H(2)O complex.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Sudipta Das et al.
Organic & biomolecular chemistry, 9(20), 7097-7104 (2011-08-27)
A weakly fluorescent cobalt(II) complex is synthesized using 2-(2-pyridyl)-benzimidazole (PBI) as a chelating fluorescent ligand and characterized by single crystal X-ray structure. This complex serves as an efficient fluorescent probe for trace level determination of aspartic acid (AspA) and glutamic
Agnieszka Jabłońska-Wawrzycka et al.
Dalton transactions (Cambridge, England : 2003), 42(17), 6092-6101 (2013-02-06)
The reactions of a mother solution of RuCl(3) with benzimidazole derivatives 2-(2'-pyridyl)benzimidazole (2,2'-PyBIm, L(1)) and 2-hydroxymethylbenzimidazole (2-CH(2)OHBIm, L(2)) yielded three novel ruthenium complexes: (H(2)L(1))(2)[Ru(III)Cl(4)(CH(3)CN)(2)](2)[Ru(IV)Cl(4)(CH(3)CN)(2)]·2Cl·6H(2)O (1), mer-[Ru(III)Cl(3)L(1)(CH(3)CN)]·L(1)·3H(2)O (2), and (HL(2))(4)[Ru(IV)Cl(6)]·2Cl·4H(2)O (3). The isolated compounds were characterised by elemental analyses, UV-Vis and
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