132624
Tetramethyl orthocarbonate
98%
Synonym(s):
Orthocarbonic acid tetramethyl ester, Tetramethoxymethane
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About This Item
Linear Formula:
C(OCH3)4
CAS Number:
Molecular Weight:
136.15
Beilstein:
1737682
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
98%
refractive index
n20/D 1.385 (lit.)
bp
114 °C (lit.)
mp
−5 °C (lit.)
density
1.023 g/mL at 25 °C (lit.)
SMILES string
COC(OC)(OC)OC
InChI
1S/C5H12O4/c1-6-5(7-2,8-3)9-4/h1-4H3
InChI key
AHJWSRRHTXRLAQ-UHFFFAOYSA-N
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General description
Tetramethyl orthocarbonate undergoes stereoselectively controlled acid hydrolysis.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
71.6 °F - closed cup
Flash Point(C)
22 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Experimental evidence for the stereoelectronically controlled hydrolysis of orthocarbonates.
Li S and Deslongchamps P.
Tetrahedron Letters, 35(31), 5641-5644 (1994)
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