- Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.
Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes.
Chemical communications (Cambridge, England) (2012-07-10)
Hajime Ito, Yuko Horita, Eiji Yamamoto
PMID22772394
摘要
The regio- and diastereoselective silaboration of aromatic alkenes with a silylboron compound proceeds in the presence of a catalytic amount of potassium tert-butoxide, providing a complementary method to the corresponding transition metal-catalyzed reactions.