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Merck

77023AST

Supelco

Astec ® CHIRALDEX B-DM 毛细管 GC 色谱柱

L × I.D. 30 m × 0.25 mm, df 0.12 μm

别名:

GC column, chiral, beta-dextran

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About This Item

分類程式碼代碼:
41115710
NACRES:
SB.54

材料

fused silica

描述

GC capillary column

包裝

pkg of 1 ea

參數

-10-200 °C temperature (isothermal)
-10-220 °C temperature (programmed)

β值

500

df

0.12 μm

技術

gas chromatography (GC): suitable

長度 × 內徑

30 m × 0.25 mm

基質活性組

non-bonded; 2,3-di-O-methyl-6-t-butyl silyl derivative of β-cyclodextrin phase

應用

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

柱類型

capillary chiral

分離技術

chiral

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一般說明

通过特殊的衍生方法,CHIRALDEX B-DM 中环糊精的浓度在聚硅氧烷载体中显著增加。该固定相对许多游离酸和碱非常有用。B-DM 能够分离可在全甲基化 β 环糊精固定相所分离的大部分物质,但分离度更高。B-DM 的选择性包括了 B-PM 和 B-PH 相的应用,但性能更加出众。

應用

它已用于气相色谱法对麻黄碱、伪麻黄碱、氯化中间体和甲基安非他明进行对映体分离。

抗化學/物理腐蝕性

温度限制:
  • -10°C 至 200°C 等温,220°C 程序性的

其他說明

我们提供各种色谱配件,包括分析注射器

法律資訊

Astec is a registered trademark of Merck KGaA, Darmstadt, Germany
CHIRALDEX is a trademark of Sigma-Aldrich Co. LLC

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分析证书(COA)

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访问文档库

Chiral gas chromatography as a tool for investigations into illicitly manufactured methylamphetamine.
Morrison, Calum, et al.
Chirality, 23.7, 519-519 (2011)
Evaluating dynamic kinetic resolution strategies in the asymmetric hydrosilylation of cyclic ketimines
Jones, Simon; Zhao, Peichao
Tetrahedron, 25 (3), 238-244 (2014)
Rh-catalyzed asymmetric hydrogenation using a furanoside monophosphite second-generation ligand library: scope and limitations
Alegre, Sabina, et al.
Tetrahedron, 25 (3), 258-262 (2014)
Synthesis of a chiral asymmetrical NCN ligand and its metallation
Sylla Dieng, Pape,et al.
Comptes Rendus Chimie, 12 (5), 560-564 (2009)
J Mydlová et al.
Journal of chromatography. A, 1150(1-2), 124-130 (2007-03-24)
The enantiomers of dialkyl 2,3-pentadienedioate undergo interconversion during gas chromatographic separation on chiral stationary phases. In this paper the on-column apparent interconversion kinetic and thermodynamic activation data were determined for dimethyl, diethyl, propylbutyl and dibutyl 2,3-pentadienedioate enantiomers by gas chromatographic

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