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Merck

55540

Sigma-Aldrich

4-氯苯甲酸汞 钠盐

≥95.0% (Hg)

别名:

4-(羟基汞)苯甲酸钠, PCMB, 对羟基汞苯甲酸 钠盐

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About This Item

经验公式(希尔记法):
C7H5HgNaO3
CAS号:
分子量:
360.69
Beilstein:
6118796
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.25

化驗

≥95.0% (Hg)

mp

≥300 °C

SMILES 字串

[Na+].O[Hg]c1ccc(cc1)C([O-])=O

InChI

1S/C7H5O2.Hg.Na.H2O/c8-7(9)6-4-2-1-3-5-6;;;/h2-5H,(H,8,9);;;1H2/q;2*+1;/p-2

InChI 密鑰

CBELQCYFTSHKPJ-UHFFFAOYSA-L

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應用

4-(Hydroxymercuri)benzoic acid is an organic mercurial compound that reacts via mercury-sulfur affinity with sulfhydryl groups in peptides, proteins and other molecules. PCMB may be used for the determination of sulfhydryl groups in proteins according to Boyer, by atomic absorption, and stopped-flow measurements, G. Castronuovo-Lepore et al.. It may be used for specific applications such as probing the active site of an enzyme such as cytochrome C oxidase. 4-(Hydroxymercuri)benzoic acid appeared mistakenly as p-chloromercuriobenzoate [PCMB] in earlier literature.

訊號詞

Danger

危險分類

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Daniel J Kutscher et al.
Analytical chemistry, 81(21), 9172-9177 (2009-10-06)
Chemical labeling with subsequent mass spectrometric detection represents a common approach for protein quantification. Whereas most methods make use of stable isotope labels from natural elements such as (2)D, (13)C, (15)N, or (18)O, artificially introduced metals have gained interest as
Emilia Bramanti et al.
Clinical chemistry, 51(6), 1007-1013 (2005-04-23)
We developed a sensitive, specific method for the low-molecular-mass thiols cysteine, cysteinylglycine, glutathione, and homocysteine and validated the method for measurement of glutathione in blood. The technique was based on reversed-phase chromatography (RPC) coupled on line with cold vapor generation
Nadia Farhat et al.
Water research, 142, 227-235 (2018-06-11)
The bacterial growth potential is important to understand and manage bacterial regrowth-related water quality concerns. Bacterial growth potential depends on growth promoting/limiting compounds, therefore, nutrient availability is the key factor governing bacterial growth potential. Selecting proper tools for bacterial growth
Yulan Rao et al.
Journal of agricultural and food chemistry, 58(3), 1462-1468 (2010-01-13)
A liquid chromatography method with mass spectrometric detection has been developed for the simultaneous determination of six thiols in the sulfur metabolic pathway, including cysteine (Cys), homocysteine (HCys), glutathione (GSH), cysteinyl-glycine (Cys-Gly), gamma-glutamyl-cysteine (Glu-Cys), and S-adenosyl-homocysteine (AdoHcy). Tris(2-carboxyethyl)phosphine (TCEP) was
Daniel J Kutscher et al.
Analytical and bioanalytical chemistry, 401(9), 2691-2698 (2011-07-21)
A method was developed for the precise and accurate determination of ovalbumin labelled with p-hydroxy-mercuribenzoic acid (pHMB) using polyacrylamide gel electrophoresis with ns-laser ablation-inductively coupled plasma mass spectrometry. Following systematic optimisation of the ablation process in terms of detection sensitivity

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