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Merck

P7875

Sigma-Aldrich

高碘酸

ReagentPlus®, ≥99.0%

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About This Item

经验公式(希尔记法):
H5IO6
CAS号:
分子量:
227.94
EC號碼:
MDL號碼:
分類程式碼代碼:
12352106
PubChem物質ID:
NACRES:
NA.21

產品線

ReagentPlus®

化驗

≥99.0%

形狀

powder or crystals

反應適用性

reagent type: oxidant

技術

toxicology assay: suitable

mp

122 °C (lit.)

溶解度

water: 100 mg/mL, clear, colorless

SMILES 字串

OI(O)(O)(O)(O)=O

InChI

1S/H5IO6/c2-1(3,4,5,6)7/h(H5,2,3,4,5,6,7)

InChI 密鑰

TWLXDPFBEPBAQB-UHFFFAOYSA-N

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相关类别

一般說明

周期酸是碘的氧化酸,通常用作强氧化剂。这种无机酸可溶于大多数溶剂,包括水和醚。

應用

周期酸可用于以下反应:      
  • 醇到酮和醛的氧化。
  • 氧化羟胺衍生物。    
  • 芳烃到醌的氧化。

它还可用作:     
  • 与醋酸铬(IV)一起作为化学计量氧化剂,用于叔 C−H 键到叔醇的氧化。     
  • 与氧化铬结合,将伯醇氧化为羧酸;烷基苯氧化为苯甲酸;环苯醚氧化为相应的内酯。      
  • 使用 FeCl3 作为催化剂,将硫化物选择性氧化为亚砜。

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1B - STOT RE 1 Oral

標靶器官

Thyroid

儲存類別代碼

5.1A - Strongly oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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