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等級
reagent grade
品質等級
蒸汽密度
2.1 (vs air)
蒸汽壓力
32.81 psi ( 55 °C)
9.21 psi ( 20 °C)
化驗
97%
形狀
liquid
自燃溫度
842 °F
expl. lim.
23 %
雜質
≤3% methyl alcohol
折射率
n20/D 1.343 (lit.)
pH值
4.0-5.0 (20 °C, 200 g/L)
bp
32-34 °C (lit.)
mp
−100 °C (lit.)
密度
0.974 g/mL at 20 °C (lit.)
SMILES 字串
[H]C(=O)OC
InChI
1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI 密鑰
TZIHFWKZFHZASV-UHFFFAOYSA-N
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應用
Methyl formate may be used to prepare formamides via amine formaylation.
訊號詞
Danger
危險分類
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 1 - STOT SE 1 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 2
閃點（°F）
-2.2 °F - closed cup
閃點（°C）
-19 °C - closed cup
Rotational isomerism in methyl formate and methyl acetate; a low-temperature matrix infrared study using thermal molecular beams.
Blom CE and Gunthard HH.
Chemical Physics Letters, 84(2), 267-271 (1981)
Lucia Lanfri et al.
The journal of physical chemistry. A, 123(29), 6130-6143 (2019-07-04)
Following photodissociation at 248 nm of gaseous methyl formate (HC(O)OCH3, 0.73 Torr) and Ar (0.14 Torr), temporally resolved vibration-rotational emission spectra of highly internally excited CO (ν ≤ 11, J ≤ 27) in the 1850-2250 cm-1 region were recorded with
Catalytic reaction of methyl formate with amines to formamides.
Deutsch J, et al.
Tetrahedron, 65(50), 10365-10369 (2009)
Marine S Da Silva et al.
Prostaglandins, leukotrienes, and essential fatty acids, 126, 64-71 (2017-10-17)
This study aimed to determine whether dairy macronutrients alter markers of inflammation and oxidative stress in endothelial cells. Human endothelial cells (HUVEC) were treated with ruminant trans fatty acids (rTFA), either trans-vaccenic acid (tVA) or trans-palmitoleic acid (tPA), whey protein
Methyl formate as a new building block in C1 chemistry.
Lee JS, et al.
Applied Catalysis, 57(1), 1-30 (1990)
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