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Merck

311375

Sigma-Aldrich

氯化锑(III)

ACS reagent, ≥99.0%

别名:

三氯化锑

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About This Item

线性分子式:
SbCl3
CAS号:
分子量:
228.12
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
eCl@ss:
38080204
PubChem物質ID:
NACRES:
NB.24
化驗:
≥99.0%
等級:
ACS reagent
形狀:
powder, crystals or chunks

等級

ACS reagent

品質等級

蒸汽密度

7.9 (vs air)

蒸汽壓力

1 mmHg ( 49 °C)

化驗

≥99.0%

形狀

powder, crystals or chunks

反應適用性

reagent type: catalyst
core: antimony

雜質

≤0.05% insol. CHCl3

mp

73.4 °C (lit.)

負離子痕跡

sulfate (SO42-): ≤0.005%

正離子痕跡

As: ≤0.02%
Ca: ≤0.005%
Cu: ≤0.001%
Fe: ≤0.002%
K: ≤0.01%
Na: ≤0.02%
Pb: ≤0.005%

SMILES 字串

Cl[Sb](Cl)Cl

InChI

1S/3ClH.Sb/h3*1H;/q;;;+3/p-3

InChI 密鑰

FAPDDOBMIUGHIN-UHFFFAOYSA-K

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應用

氯化锑(III)(SbCl3)是一种路易斯酸催化剂,用于各种有机反应,如聚合、Friedel-Crafts 酰化、NaBH4 还原、环氧化合物开环、三烷基醚裂解、Biginelli 反应和氯化反应。它也被用作合成其他锑盐的前体。

象形圖

CorrosionEnvironment

訊號詞

Danger

危險聲明

危險分類

Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析证书(COA)

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Synthesis, structural characterization and cytotoxicity of the antimony (III) chloride complex with N, N-dicyclohexyldithiooxamide.
Ozturk II, et al.
Polyhedron, 52, 1403-1410 (2013)
Antimony (III) chloride-catalysed Biginelli reaction: a versatile method for the synthesis of dihydropyrimidinones through a different reaction mechanism
Cepanec I, et al.
Tetrahedron, 63(48), 11822-11827 (2007)
Antimony (III) chloride-catalyzed ring opening of epoxides with anilines.
Singh MC and Peddinti RK.
Tetrahedron Letters, 48(41), 7354-7357 (2007)
Nucleic acid related compounds. 79. Efficient conversions of thioethers to. alpha.-fluoro thioethers with DAST or DAST/antimony (III) chloride.
Robins MJ and Wnuk SF.
The Journal of Organic Chemistry, 58(15), 3800-3800 (1993)
T Gebel
Mutation research, 412(3), 213-218 (1998-05-26)
Arsenic and antimony are two semimetals sharing some chemical as well as toxicological properties. Both elements are clastogenic but not point mutagenic in their trivalent state of valency. Environmental exposure to arsenic was proven to be associated with increased rates

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