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蒸汽壓力
1 mmHg ( 100 °C)
品質等級
產品線
ReagentPlus®
化驗
99%
形狀
crystalline solid
crystals or chunks
反應適用性
reagent type: catalyst
core: aluminum
pH值
2.5-3.5 (20 °C)
SMILES 字串
Cl[Al](Cl)Cl.O.O.O.O.O.O
InChI
1S/Al.3ClH.6H2O/h;3*1H;6*1H2/q+3;;;;;;;;;/p-3
InChI 密鑰
JGDITNMASUZKPW-UHFFFAOYSA-K
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一般說明
氯化铝六水合物是一种不易燃的化合物，广泛用作有机合成中的催化剂。除极易溶于水外，还溶于乙醇、乙醚、甘油、丙二醇和乙腈。它有很多用途，包括原油提炼、生产除臭剂和止汗产品、织物染色、纺织品整理。
應用
氯化铝六水合物用作催化剂：
- 用于醇或酚和3,4-二氢-2H-吡喃（DHP）合成对应的THP（四氢吡喃）醚。
- 用于乙酰丙酸和乙醇直接酯化生产乙酰丙酸乙酯。
- 用于由酮和醛合成gem-二氢过氧化物。
法律資訊
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Corr. 1B - STOT RE 1
標靶器官
Lungs
安全危害
儲存類別代碼
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
水污染物質分類（WGK）
WGK 1
閃點（°F）
Not applicable
閃點（°C）
Not applicable
其他客户在看
[Axillary hyperhydrosis. Local treatment with 25% aluminum chloride hexahydrate in absolute alcohol].
F Brandrup et al.
Ugeskrift for laeger, 140(35), 2106-2109 (1978-08-28)
Aluminium (III) chloride hexahydrate: an efficient and versatile reagent in organic synthesis.
Sarma SD, et al.
ARKIVOC (Gainesville, FL, United States), 1, 243-263 (2013)
Ingrid Siemund et al.
Contact dermatitis, 77(5), 288-296 (2017-07-12)
Contact allergy to aluminium has been reported more frequently in recent years. It has been pointed out that positive patch test reactions to aluminium may not be reproducible on retesting. To investigate possible variations in patch test reactivity to aluminium
Mark Baranov et al.
Inorganic chemistry, 58(13), 8877-8883 (2019-06-30)
While sophisticated computational methods can predict 31P NMR spectra of phosphorus atoms encapsulated within Keggin-derived heteropoly tungstate and molybdate cluster anions, calculated and experimental chemical shift values typically deviate considerably from one another. Motivated by the observation that experimentally determined
Solvent-free tetrahydropyranylation (THP) of alcohols and phenols and their regeneration by catalytic aluminum chloride hexahydrate.
Namboodiri VV and Varma RS.
Tetrahedron Letters, 43(7), 1143-1146 (2002)
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