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Merck

185302

Sigma-Aldrich

二异丙基醚

ReagentPlus®, 99%, contains either BHT or hydroquinone as stabilizer

别名:

异丙醚

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About This Item

线性分子式:
(CH3)2CHOCH(CH3)2
CAS号:
分子量:
102.17
Beilstein:
1731256
EC號碼:
MDL號碼:
分類程式碼代碼:
12191502
PubChem物質ID:
NACRES:
NA.07

蒸汽密度

3.5 (vs air)

品質等級

蒸汽壓力

120 mmHg ( 20 °C)

產品線

ReagentPlus®

化驗

99%

形狀

liquid

自燃溫度

827 °F

expl. lim.

1-21 %, 100 °F

折射率

n20/D 1.367 (lit.)

bp

68-69 °C (lit.)

mp

−85 °C (lit.)

密度

0.725 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)OC(C)C

InChI

1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3

InChI 密鑰

ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

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一般說明

Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent. Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed. Its efficacy as a fuel additive has been reported. When released in the atmosphere, it undergoes photodecomposition by reacting with OH radicals. Kinetics and mechanism of its reaction in atmosphere have been reported.

應用

Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - STOT SE 3

標靶器官

Central nervous system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-20.2 °F - closed cup

閃點(°C)

-29 °C - closed cup


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Atmospheric chemistry of automotive fuel additives: diisopropyl ether.
Wallington TJ, et al.
Environmental Science & Technology, 27(1), 98-104 (1993)
Eagleson M.
Concise Encyclopedia Chemistry, 325-325 (1994)
Single stage synthesis of diisopropyl ether-an alternative octane enhancer for lead-free petrol.
Heese FP, et al.
Catalysis Today, 49(1), 327-335 (1999)
Novel (R)-oxynitrilase sources for the synthesis of (R)-cyanohydrins in diisopropyl ether.
Kiljunen E and Kanerva LT.
Tetrahedron Asymmetry, 8(8), 1225-1234 (1997)
A Azim et al.
Bioorganic & medicinal chemistry, 9(5), 1345-1348 (2001-05-30)
An efficient lipase catalysed synthesis of optically enriched alpha-halogenated amides with concomitant optical enrichment of the starting alpha-haloesters is described. Candida antarctica lipase (CAL) was found to be a better catalyst over porcine pancreatic lipase (PPL) and Candida cylindracea lipase

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