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Merck
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文件

D152927

Sigma-Aldrich

碳酸二甲酯

greener alternative

ReagentPlus®, 99%

别名:

碳酸二甲酯

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About This Item

线性分子式:
(CH3O)2CO
CAS号:
616-38-6
分子量:
90.08
Beilstein:
635821
EC號碼:
210-478-4
MDL號碼:
MFCD00008420
分類程式碼代碼:
12352100
PubChem物質ID:
57654072
NACRES:
NA.21

蒸汽密度

3.1 (vs air)

品質等級

200

蒸汽壓力

18 mmHg ( 21.1 °C)

產品線

ReagentPlus®

化驗

99%

形狀

liquid

環保替代產品特色

Less Hazardous Chemical Syntheses
Safer Solvents and Auxiliaries
Design for Degradation
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

折射率

n20/D 1.368 (lit.)

bp

90 °C (lit.)

mp

2-4 °C (lit.)

密度

1.069 g/mL at 25 °C (lit.)

環保替代類別

, Aligned

SMILES 字串

O=C(OC)OC

InChI

1S/C3H6O3/c1-5-3(4)6-2/h1-2H3

InChI 密鑰

IEJIGPNLZYLLBP-UHFFFAOYSA-N

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相关类别

一般說明

碳酸二甲酯(DMC)是一种多功能、无毒、可生物降解的试剂，具有可调节的化学反应性。它可作为硫酸二甲酯或卤代甲烷和光气的绿色替代物，可用于甲基化和羧化反应。对二氧化碳和甲醇形成 DMC 的碱催化反应进行研究。报道 DMC 的各种热力学参数。

我们致力于为您带来更环保的替代产品，以符合一项或多项绿色化学12项原则。此产品更加绿色环保，是传统溶剂和化学制剂的替代品。点击此处以获取更多信息。

應用

碳酸二甲酯可用于合成：
  • 苯酚与碳酸苯酯的酯交换反应。
  • 碳酸二苯酯与碳酸甲基苯酯通过酯交换反应生成碳酸二苯酯。
  • 氨基甲酸甲酯，异氰酸酯合成的原料。
  • 在 550-600K 下与二氧化硅反应生成四甲氧基硅烷。

特點和優勢

更绿色环保的溶剂

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

Flame
GHS02

訊號詞

Danger

危險聲明

H225

危險分類

Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 1

閃點（°F）

60.8 °F - closed cup

閃點（°C）

16 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Choose from one of the most recent versions:

分析证书(COA)

Lot/Batch Number
MKCQ2142
STBK2322
MKCP0343
MKCN2994
MKCM0309

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Direct synthesis of dimethyl carbonate from carbon dioxide and methanol catalyzed by base.
Fang S and Fujimoto K.
Applied Catalysis A: General, 142(1), L1-L3 (1996)
Thermodynamic Properties of Dimethyl Carbonatea).
Zhou Y, et al.
Journal of Physical and Chemical Reference Data, 40(4), 043106-043106 (2011)
Jana Engeldinger et al.
Physical chemistry chemical physics : PCCP, 14(7), 2183-2191 (2011-11-18)
The simultaneous combination of steady state isotopic transient kinetic analysis (SSITKA) with diffuse reflectance Fourier transform spectroscopy (DRIFTS) and mass spectrometric (MS) analysis was applied to study the oxidative carbonylation of methanol (MeOH) to dimethyl carbonate (DMC) on a CuY
Catalysis in the production and reactions of dimethyl carbonate, an environmentally benign building block.
Ono Y.
Applied Catalysis A: General, 155(2), 133-166 (1997)
Liping Zhang et al.
Bioresource technology, 101(21), 8144-8150 (2010-07-02)
The transesterification of palm oil with dimethyl carbonate (DMC) for preparing biodiesel has been studied in solvent-free system at the catalysis of potassium hydroxide (KOH) as heterogeneous catalyst. Fatty acid methyl esters (FAMEs) were analyzed by GC with internal standard
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