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Merck

439223

Sigma-Aldrich

二氯甲烷

suitable for HPLC, ≥99.9%, contains 40-150 ppm amylene as stabilizer

别名:

亚甲基氯

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About This Item

经验公式(希尔记法):
CH2Cl2
CAS号:
分子量:
84.93
Beilstein:
1730800
EC號碼:
MDL號碼:
分類程式碼代碼:
12190000
PubChem物質ID:
NACRES:
NA.21

蒸汽密度

2.9 (vs air)

品質等級

蒸汽壓力

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

化驗

≥99.9%

形狀

liquid

自燃溫度

1223 °F

包含

40-150 ppm amylene as stabilizer

expl. lim.

22 %

技術

HPLC: suitable

雜質

Free halogens, passes test
≤0.0003 meq/g Titr. acid
≤0.02% water

蒸發殘留物

<0.0003%

顏色

APHA: ≤10
clear

折射率

n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−95 °C (lit.)

密度

1.325 g/mL at 25 °C (lit.)

&lambda ;

H2O reference

紫外吸收

λ: 235 nm Amax: 1.00
λ: 240 nm Amax: 0.20
λ: 250 nm Amax: 0.05
λ: 260 nm Amax: 0.02
λ: 340-400 nm Amax: 0.01

適合性

passes test for HPLC

SMILES 字串

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI 密鑰

YMWUJEATGCHHMB-UHFFFAOYSA-N

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一般說明

Dichloromethane (DCM) is a chlorinated organic solvent with a wide range of industrial applications. It has C2v symmetry, low boiling point, high density and is immiscible in water. Degradation of DCM by various methods has been reported. Ultrasonic absorption studies of liquid DCM shows strong relaxation effect. A study reports the dielectric characteristics of DCM over a wide frequency range. DCM is susceptible to degradation with time, which can be suppressed by adding amylene as a stabilizer.

應用

符合 ACS 规范。
Dichloromethane (Methylene chloride) may be used in the following processes:
  • To compose ultrasonic baths for cleaning and protection of aluminum coating over atactic-PMMA (poly(methyl methacrylate)) for dielectric studies.
  • Preparation of AMBF3 (ammoniomethyltrifluoroborate)-conjugated biomolecules.
  • Sample preparation for GC-MS (Gas Chromatography-Mass Spectrometry) analysis.
  • Preparation of ammonium acetate solvent mixture in combination with isopropanol, acetonitrile and water for mass spectral analysis of neutral lipids.
  • Quantification of glutathione (GSH) and glutathione disulfide (GSSG) in biological samples by HPLC and spectrophotometry.
  • As an extractant for 2,2-dithioethyl-4-(2′-pyridyl)-4-butyro-γ-lactone.

準備報告

产品经过 0.2μm 过滤器过滤

象形圖

Health hazardExclamation mark

訊號詞

Warning

危險分類

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Central nervous system

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 2

閃點(°F)

does not flash

閃點(°C)

does not flash

個人防護裝備

Eyeshields, Faceshields, Gloves


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分析证书(COA)

Lot/Batch Number

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访问文档库

Daniela Giustarini et al.
Nature protocols, 8(9), 1660-1669 (2013-08-10)
This protocol describes a procedure for determining glutathione (GSH) and glutathione disulfide (GSSG) concentrations in blood and other tissues. Artifactual oxidation to GSSG of 5-15% of the GSH found in a sample can occur during deproteination of biological samples with
Rodney C Baker et al.
Methods in enzymology, 538, 89-105 (2014-02-18)
Mass spectrometry technology has enabled significant advances in detailing the alterations of the lipidome in response to pathological conditions or experimental manipulations. Lipids comprise a wide range of compounds with functions that include structural, intracellular signaling, trafficking, and storage. Characterization
Jane A Mullaney et al.
Journal of agricultural and food chemistry, 61(12), 3039-3046 (2013-03-07)
Glucosinolates from the genus Brassica can be converted into bioactive compounds known to induce phase II enzymes, which may decrease the risk of cancers. Conversion via hydrolysis is usually by the brassica enzyme myrosinase, which can be inactivated by cooking
Vitamin B12-mediated hydrodechlorination of dichloromethane by bimetallic Cu/Al particles.
Huang CC, et al.
Chemical Engineering Journal, 273, 413-420 (2015)
Dichloromethane Detection Based on Near-Infrared Absorptive Sensing.
Han JH and Yoon SM
IEEE Journal of Selected Topics in Quantum Electronics, 18(5), 1547-1552 (2012)

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