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Merck

439142

Supelco

氯仿

suitable for HPLC, ≥99.8%, contains 0.5-1.0% ethanol as stabilizer

别名:

三氯甲烷

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About This Item

经验公式(希尔记法):
CHCl3
CAS号:
分子量:
119.38
Beilstein:
1731042
MDL號碼:
分類程式碼代碼:
12190000
PubChem物質ID:
化驗:
≥99.8%
技術:
HPLC: suitable
應用:
food and beverages
bp:
60.5-61.5 °C (lit.)
蒸汽壓力:
160 mmHg ( 20 °C)

蒸汽密度

4.1 (vs air)

品質等級

蒸汽壓力

160 mmHg ( 20 °C)

化驗

≥99.8%

形狀

liquid

包含

0.5-1.0% ethanol as stabilizer

包裝

PVC-coated bottle of 4, 4x4 L

技術

HPLC: suitable

雜質

<0.01% water

蒸發殘留物

<0.0003%

顏色

APHA: ≤10

折射率

n20/D 1.445 (lit.)

bp

60.5-61.5 °C (lit.)

mp

−63 °C (lit.)

密度

1.48 g/mL at 25 °C
1.492 g/mL at 25 °C (lit.)

正離子痕跡

Pb: ≤0.05 ppm

&lambda ;

H2O reference

紫外吸收

λ: 245 nm Amax: 1.00
λ: 255 nm Amax: 0.15
λ: 260 nm Amax: 0.15
λ: 270 nm Amax: 0.02
λ: 290-400 nm Amax: 0.01

應用

food and beverages

SMILES 字串

ClC(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H

InChI 密鑰

HEDRZPFGACZZDS-UHFFFAOYSA-N

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一般說明

Chloroform is a colorless, volatile chlorinated organic solvent whose vapors have a narcotic effect. It is susceptible to degradation with time, which can be suppressed by adding ethanol as a stabilizer. Since ethanol is added in higher concentration it leads to increase in polarity which may have a potential influence on some of the applications. Reports suggest that chloroform stabilized with ethanol reduces chances on creating artifacts during the chromatographic separation after extraction of anthracyclines from biological matrices.

應用

Chloroform was used as an organic phase in the methylene blue (MB) two-phase titration process for estimating the cationic surfactant content in high salinity brine.
It may be used as:
  • Solvent for electropolymerization.
  • Solvent for recrystallization.
  • Extractant in solvent extraction process.

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象形圖

Skull and crossbonesHealth hazard

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

標靶器官

Central nervous system, Liver,Kidney

儲存類別代碼

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

does not flash

閃點(°C)

does not flash


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Solubility controlled electropolymerisation and study of the impact of regioregularity on the spectroelectrochemical properties of thin films of poly (3-octylthiophenes).
Jarosz T, et al.
Electrochimica Acta, 122, 66-71 (2014)
Traces of phosgene in chloroform: Consequences for extraction of anthracyclines.
Maudens KE, et al.
Journal of Chromatography. B, Biomedical Applications, 848(2), 384-390 (2007)
Leyu Cui et al.
Analytical chemistry, 86(22), 11055-11061 (2014-11-05)
The methylene blue (MB) two-phase titration method is a rapid and efficient method for determining the concentrations of anionic surfactants. The point at which the aqueous and chloroform phases appear equally blue is called Epton's end point. However, many inorganic
Eagleson M.
Concise Encyclopedia Chemistry, 216-216 (1994)
Analytical chemistry in a drop. Solvent extraction in a microdrop.
Liu H and Dasgupta PK.
Analytical Chemistry, 68(11), 1817-1821 (1996)

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